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Spin Crossover and Long‐Lived Excited States in a Reduced Molecular Ruby
The chromium(III) complex [Cr(III)(ddpd)(2)](3+) (molecular ruby; ddpd=N,N′‐dimethyl‐N,N′‐dipyridine‐2‐yl‐pyridine‐2,6‐diamine) is reduced to the genuine chromium(II) complex [Cr(II)(ddpd)(2)](2+) with d(4) electron configuration. This reduced molecular ruby represents one of the very few chromium(I...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318154/ https://www.ncbi.nlm.nih.gov/pubmed/32167607 http://dx.doi.org/10.1002/chem.202001237 |