Cargando…
Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus
The chemical bulk reductive covalent functionalization of thin‐layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization w...
| Autores principales: | , , , , , , , , , , , , , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318246/ https://www.ncbi.nlm.nih.gov/pubmed/30675972 http://dx.doi.org/10.1002/anie.201811181 |
| _version_ | 1783550803117604864 |
|---|---|
| author | Wild, Stefan Fickert, Michael Mitrovic, Aleksandra Lloret, Vicent Neiss, Christian Vidal‐Moya, José Alejandro Rivero‐Crespo, Miguel Ángel Leyva‐Pérez, Antonio Werbach, Katharina Peterlik, Herwig Grabau, Mathias Wittkämper, Haiko Papp, Christian Steinrück, Hans‐Peter Pichler, Thomas Görling, Andreas Hauke, Frank Abellán, Gonzalo Hirsch, Andreas |
| author_facet | Wild, Stefan Fickert, Michael Mitrovic, Aleksandra Lloret, Vicent Neiss, Christian Vidal‐Moya, José Alejandro Rivero‐Crespo, Miguel Ángel Leyva‐Pérez, Antonio Werbach, Katharina Peterlik, Herwig Grabau, Mathias Wittkämper, Haiko Papp, Christian Steinrück, Hans‐Peter Pichler, Thomas Görling, Andreas Hauke, Frank Abellán, Gonzalo Hirsch, Andreas |
| author_sort | Wild, Stefan |
| collection | PubMed |
| description | The chemical bulk reductive covalent functionalization of thin‐layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes. |
| format | Online Article Text |
| id | pubmed-7318246 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2019 |
| publisher | John Wiley and Sons Inc. |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-73182462020-06-29 Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus Wild, Stefan Fickert, Michael Mitrovic, Aleksandra Lloret, Vicent Neiss, Christian Vidal‐Moya, José Alejandro Rivero‐Crespo, Miguel Ángel Leyva‐Pérez, Antonio Werbach, Katharina Peterlik, Herwig Grabau, Mathias Wittkämper, Haiko Papp, Christian Steinrück, Hans‐Peter Pichler, Thomas Görling, Andreas Hauke, Frank Abellán, Gonzalo Hirsch, Andreas Angew Chem Int Ed Engl Communications The chemical bulk reductive covalent functionalization of thin‐layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes. John Wiley and Sons Inc. 2019-03-21 2019-04-16 /pmc/articles/PMC7318246/ /pubmed/30675972 http://dx.doi.org/10.1002/anie.201811181 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. |
| spellingShingle | Communications Wild, Stefan Fickert, Michael Mitrovic, Aleksandra Lloret, Vicent Neiss, Christian Vidal‐Moya, José Alejandro Rivero‐Crespo, Miguel Ángel Leyva‐Pérez, Antonio Werbach, Katharina Peterlik, Herwig Grabau, Mathias Wittkämper, Haiko Papp, Christian Steinrück, Hans‐Peter Pichler, Thomas Görling, Andreas Hauke, Frank Abellán, Gonzalo Hirsch, Andreas Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus |
| title | Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus |
| title_full | Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus |
| title_fullStr | Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus |
| title_full_unstemmed | Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus |
| title_short | Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus |
| title_sort | lattice opening upon bulk reductive covalent functionalization of black phosphorus |
| topic | Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318246/ https://www.ncbi.nlm.nih.gov/pubmed/30675972 http://dx.doi.org/10.1002/anie.201811181 |
| work_keys_str_mv | AT wildstefan latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT fickertmichael latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT mitrovicaleksandra latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT lloretvicent latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT neisschristian latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT vidalmoyajosealejandro latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT riverocrespomiguelangel latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT leyvaperezantonio latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT werbachkatharina latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT peterlikherwig latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT grabaumathias latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT wittkamperhaiko latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT pappchristian latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT steinruckhanspeter latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT pichlerthomas latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT gorlingandreas latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT haukefrank latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT abellangonzalo latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus AT hirschandreas latticeopeninguponbulkreductivecovalentfunctionalizationofblackphosphorus |