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Gold(I)‐Catalyzed Haloalkynylation of Aryl Alkynes: Two Pathways, One Goal

Haloalkynylation reactions provide an efficient method for the simultaneous introduction of a halogen atom and an acetylenic unit. For the first time, we report a gold(I)‐catalyzed haloalkynylation of aryl alkynes that delivers exclusively the cis addition product. This method enables the simple syn...

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Detalles Bibliográficos
Autores principales: Kreuzahler, Mathis, Haberhauer, Gebhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318269/
https://www.ncbi.nlm.nih.gov/pubmed/32078231
http://dx.doi.org/10.1002/anie.201916027