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Regioselective Insertion of Aluminum(I) in the cyclo‐P(5) Ring of Pentaphosphaferrocene

A route to directly access mixed Al–Fe polyphosphide complexes was developed. The reactivity of pentaphosphaferrocene, [Cp*Fe(η (5)‐P(5))] (Cp*=C(5)Me(5)), with two different low‐valent aluminum compounds was investigated. The steric and electronic environment around the [Al(I)] centre are found to...

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Detalles Bibliográficos
Autores principales:	Yadav, Ravi, Simler, Thomas, Goswami, Bhupendra, Schoo, Christoph, Köppe, Ralf, Dey, Subhayan, Roesky, Peter W.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318284/ https://www.ncbi.nlm.nih.gov/pubmed/32187800 http://dx.doi.org/10.1002/anie.202002774

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