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Double‐Gyroid Nanostructure Formation by Aggregation‐Induced Atropisomerization and Co‐Assembly of Ionic Liquid‐Crystalline Amphiphiles

We report a new molecular‐design principle for creating double‐gyroid nanostructured molecular assemblies based on atropisomerization. Ionic amphiphiles containing two imidazolium rings close to each other were designed and synthesized. NMR data revealed that the rotation of the imidazolium rings is...

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Detalles Bibliográficos
Autores principales: Uemura, Nanami, Kobayashi, Tsubasa, Yoshida, Shintaro, Li, Ya‐xin, Goossens, Karel, Zeng, Xiangbing, Watanabe, Go, Ichikawa, Takahiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318300/
https://www.ncbi.nlm.nih.gov/pubmed/32128958
http://dx.doi.org/10.1002/anie.202000424