A HF Loaded Lewis‐Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions

The very strong Lewis acid aluminium chlorofluoride (ACF) was loaded with anhydrous HF. The interaction between the surface of the catalyst and HF was investigated using a variety of characterization methods, which revealed the formation of polyfluorides. Moreover, the reactivity of the HF‐loaded AC...

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Autores principales: Kervarec, Maëva‐Charlotte, Kemnitz, Erhard, Scholz, Gudrun, Rudić, Svemir, Braun, Thomas, Jäger, Christian, Michalchuk, Adam A. L., Emmerling, Franziska
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318592/
https://www.ncbi.nlm.nih.gov/pubmed/32315479
http://dx.doi.org/10.1002/chem.202001627
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author Kervarec, Maëva‐Charlotte
Kemnitz, Erhard
Scholz, Gudrun
Rudić, Svemir
Braun, Thomas
Jäger, Christian
Michalchuk, Adam A. L.
Emmerling, Franziska
author_facet Kervarec, Maëva‐Charlotte
Kemnitz, Erhard
Scholz, Gudrun
Rudić, Svemir
Braun, Thomas
Jäger, Christian
Michalchuk, Adam A. L.
Emmerling, Franziska
author_sort Kervarec, Maëva‐Charlotte
collection PubMed
description The very strong Lewis acid aluminium chlorofluoride (ACF) was loaded with anhydrous HF. The interaction between the surface of the catalyst and HF was investigated using a variety of characterization methods, which revealed the formation of polyfluorides. Moreover, the reactivity of the HF‐loaded ACF towards the hydrofluorination of alkynes was studied.
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spelling pubmed-73185922020-06-29 A HF Loaded Lewis‐Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions Kervarec, Maëva‐Charlotte Kemnitz, Erhard Scholz, Gudrun Rudić, Svemir Braun, Thomas Jäger, Christian Michalchuk, Adam A. L. Emmerling, Franziska Chemistry Full Papers The very strong Lewis acid aluminium chlorofluoride (ACF) was loaded with anhydrous HF. The interaction between the surface of the catalyst and HF was investigated using a variety of characterization methods, which revealed the formation of polyfluorides. Moreover, the reactivity of the HF‐loaded ACF towards the hydrofluorination of alkynes was studied. John Wiley and Sons Inc. 2020-05-26 2020-06-05 /pmc/articles/PMC7318592/ /pubmed/32315479 http://dx.doi.org/10.1002/chem.202001627 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Full Papers
Kervarec, Maëva‐Charlotte
Kemnitz, Erhard
Scholz, Gudrun
Rudić, Svemir
Braun, Thomas
Jäger, Christian
Michalchuk, Adam A. L.
Emmerling, Franziska
A HF Loaded Lewis‐Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions
title A HF Loaded Lewis‐Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions
title_full A HF Loaded Lewis‐Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions
title_fullStr A HF Loaded Lewis‐Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions
title_full_unstemmed A HF Loaded Lewis‐Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions
title_short A HF Loaded Lewis‐Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions
title_sort hf loaded lewis‐acidic aluminium chlorofluoride for hydrofluorination reactions
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318592/
https://www.ncbi.nlm.nih.gov/pubmed/32315479
http://dx.doi.org/10.1002/chem.202001627
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