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Highly Active Superbulky Alkaline Earth Metal Amide Catalysts for Hydrogenation of Challenging Alkenes and Aromatic Rings

Two series of bulky alkaline earth (Ae) metal amide complexes have been prepared: Ae[N(TRIP)(2)](2) (1‐Ae) and Ae[N(TRIP)(DIPP)](2) (2‐Ae) (Ae=Mg, Ca, Sr, Ba; TRIP=SiiPr(3), DIPP=2,6‐diisopropylphenyl). While monomeric 1‐Ca was already known, the new complexes have been structurally characterized. M...

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Detalles Bibliográficos
Autores principales:	Martin, Johannes, Knüpfer, Christian, Eyselein, Jonathan, Färber, Christian, Grams, Samuel, Langer, Jens, Thum, Katharina, Wiesinger, Michael, Harder, Sjoerd
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318605/ https://www.ncbi.nlm.nih.gov/pubmed/32045078 http://dx.doi.org/10.1002/anie.202001160

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