Reactivity of Binary and Ternary Sulfur Halides towards Transition‐Metal Compounds

Binary sulfur fluorides exhibit an interesting reactivity towards transition metal complexes. They open up routes for the generation of sulfur‐containing building blocks. Often ligands with particular properties can be constructed. This includes their ability to transfer sulfur atoms or polysulfide...

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Detalles Bibliográficos
Autores principales: Dirican, Dilcan, Pfister, Nils, Wozniak, Martin, Braun, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Minireviews
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318666/
https://www.ncbi.nlm.nih.gov/pubmed/31840851
http://dx.doi.org/10.1002/chem.201904493
Descripción
Sumario:Binary sulfur fluorides exhibit an interesting reactivity towards transition metal complexes. They open up routes for the generation of sulfur‐containing building blocks. Often ligands with particular properties can be constructed. This includes their ability to transfer sulfur atoms or polysulfide units as well as fluorination reactions. This Minireview provides an insight into the reactivity of the binary and ternary sulfur halides S(2)Cl(2), SCl(2), SF(4), SF(6) and SF(5)Cl towards transition‐metal compounds.

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