Magnetic Phase Transitions in a Ni(4)O(4)‐Cubane‐Based Metal–Organic Framework

An unprecedented spin cluster‐based network architecture {[Ni(II) (2)(pdaa)(OH)(2)(H(2)O)](n) (H(2)pdaa=1,4‐phenylene diacetic acid)}, comprising 1D linear chains of Ni(II) ions crosslinked via Ni(4)O(4) cubanes, forms under hydrothermal conditions; this 3D coordination network exhibits magnetic ord...

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Autores principales: Nadeem, Muhammad Arif, Ng, Maggie Chai Cin, van Leusen, Jan, Kögerler, Paul, Stride, John Arron
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318679/
https://www.ncbi.nlm.nih.gov/pubmed/32242986
http://dx.doi.org/10.1002/chem.202000867
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author Nadeem, Muhammad Arif
Ng, Maggie Chai Cin
van Leusen, Jan
Kögerler, Paul
Stride, John Arron
author_facet Nadeem, Muhammad Arif
Ng, Maggie Chai Cin
van Leusen, Jan
Kögerler, Paul
Stride, John Arron
author_sort Nadeem, Muhammad Arif
collection PubMed
description An unprecedented spin cluster‐based network architecture {[Ni(II) (2)(pdaa)(OH)(2)(H(2)O)](n) (H(2)pdaa=1,4‐phenylene diacetic acid)}, comprising 1D linear chains of Ni(II) ions crosslinked via Ni(4)O(4) cubanes, forms under hydrothermal conditions; this 3D coordination network exhibits magnetic ordering at 23.9 K as well as a second magnetic ordering process at 2.8 K likely associated with a structural phase transition.
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spelling pubmed-73186792020-06-29 Magnetic Phase Transitions in a Ni(4)O(4)‐Cubane‐Based Metal–Organic Framework Nadeem, Muhammad Arif Ng, Maggie Chai Cin van Leusen, Jan Kögerler, Paul Stride, John Arron Chemistry Full Papers An unprecedented spin cluster‐based network architecture {[Ni(II) (2)(pdaa)(OH)(2)(H(2)O)](n) (H(2)pdaa=1,4‐phenylene diacetic acid)}, comprising 1D linear chains of Ni(II) ions crosslinked via Ni(4)O(4) cubanes, forms under hydrothermal conditions; this 3D coordination network exhibits magnetic ordering at 23.9 K as well as a second magnetic ordering process at 2.8 K likely associated with a structural phase transition. John Wiley and Sons Inc. 2020-05-14 2020-06-18 /pmc/articles/PMC7318679/ /pubmed/32242986 http://dx.doi.org/10.1002/chem.202000867 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Full Papers
Nadeem, Muhammad Arif
Ng, Maggie Chai Cin
van Leusen, Jan
Kögerler, Paul
Stride, John Arron
Magnetic Phase Transitions in a Ni(4)O(4)‐Cubane‐Based Metal–Organic Framework
title Magnetic Phase Transitions in a Ni(4)O(4)‐Cubane‐Based Metal–Organic Framework
title_full Magnetic Phase Transitions in a Ni(4)O(4)‐Cubane‐Based Metal–Organic Framework
title_fullStr Magnetic Phase Transitions in a Ni(4)O(4)‐Cubane‐Based Metal–Organic Framework
title_full_unstemmed Magnetic Phase Transitions in a Ni(4)O(4)‐Cubane‐Based Metal–Organic Framework
title_short Magnetic Phase Transitions in a Ni(4)O(4)‐Cubane‐Based Metal–Organic Framework
title_sort magnetic phase transitions in a ni(4)o(4)‐cubane‐based metal–organic framework
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318679/
https://www.ncbi.nlm.nih.gov/pubmed/32242986
http://dx.doi.org/10.1002/chem.202000867
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