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Zn(II)-to-Cu(II) Transmetalation in an Amide Functionalized Complex and Catalytic Applications in Styrene Oxidation and Nitroaldol Coupling

The mononuclear zinc(II) complex cis-[ZnL(2)(H(2)O)(2)] (1; L = 4-(pyridin-3-ylcarbamoyl)benzoate) was synthesized and characterized. By soaking crystals of 1 in a mixture of DMF-H(2)O solution containing a slight excess of Cu(NO(3))(2) × 3H(2)O a transmetalation reaction occurred affording the rela...

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Detalles Bibliográficos
Autores principales:	Paul, Anup, Martins, Luísa M. D. R. S., Karmakar, Anirban, Kuznetsov, Maxim L., C. Guedes da Silva, M. Fátima, Pombeiro, Armando J. L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2020
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7321079/ https://www.ncbi.nlm.nih.gov/pubmed/32517273 http://dx.doi.org/10.3390/molecules25112644

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