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Acid‐Catalyzed Rearrangements of 3‐Aryloxirane‐2‐Carboxamides: Novel DFT Mechanistic Insights

Efficient synthesis of 3‐arylquinolin‐2(1H)‐ones and N‐(2‐carboxyaryl)‐oxalamides from protic acid‐catalyzed rearrangements of 3‐aryloxirane‐2‐carboxamides was achieved recently but not well understood. In contrast to the classical Meinwald rearrangement, extensive DFT calculations reveal that the p...

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Detalles Bibliográficos
Autores principales:	Qu, Zheng‐Wang, Zhu, Hui, Katsyuba, Sergey A., Mamedova, Vera L., Mamedov, Vakhid A., Grimme, Stefan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7327482/ https://www.ncbi.nlm.nih.gov/pubmed/32626644 http://dx.doi.org/10.1002/open.202000110

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