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Cost effective liquid phase exfoliation of MoS(2) nanosheets and photocatalytic activity for wastewater treatment enforced by visible light

Scalable production of high-quality MoS(2) nanosheets remains challenging for industrial applications and research in basic sciences. N-methyl-2pyrrolidine (NMP) is a commonly used solvent for exfoliation of MoS(2) nanosheets having further disadvantage of slow volatility rate. The present study dem...

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Autores principales: Sahoo, Dhirendra, Kumar, Birendra, Sinha, Jaivardhan, Ghosh, Subhasis, Roy, Susanta Sinha, Kaviraj, Bhaskar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7330046/
https://www.ncbi.nlm.nih.gov/pubmed/32612159
http://dx.doi.org/10.1038/s41598-020-67683-2
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author Sahoo, Dhirendra
Kumar, Birendra
Sinha, Jaivardhan
Ghosh, Subhasis
Roy, Susanta Sinha
Kaviraj, Bhaskar
author_facet Sahoo, Dhirendra
Kumar, Birendra
Sinha, Jaivardhan
Ghosh, Subhasis
Roy, Susanta Sinha
Kaviraj, Bhaskar
author_sort Sahoo, Dhirendra
collection PubMed
description Scalable production of high-quality MoS(2) nanosheets remains challenging for industrial applications and research in basic sciences. N-methyl-2pyrrolidine (NMP) is a commonly used solvent for exfoliation of MoS(2) nanosheets having further disadvantage of slow volatility rate. The present study demonstrates a cost-effective facile chemical route to synthesize few-layer MoS(2) nanosheets using acetone as a solvent and by varying bulk initial concentration of samples to scale up the production in large scale to fulfill the demand for potential applications. In our study, we aim to obtain stable growth of high quality few layer MoS(2) nanosheets by long sonication times. Optical absorption spectra, Raman spectra, size of nanosheets and layer thickness of as-grown MoS(2) nanosheets were found to be matching with those obtained from other synthesis methods. Effective photocatalytic performance of MoS(2) nanosheets without being consumed as a reactant was experimented by decomposing Methylene Blue dye in aqueous solution under irradiation of visible light. This study provides an idea to synthesize low-cost, sustainable and efficient photocatalytic material in large scale for the next generation to control water pollution quite efficiently by protecting the environment from the contamination coming from these dyes.
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spelling pubmed-73300462020-07-06 Cost effective liquid phase exfoliation of MoS(2) nanosheets and photocatalytic activity for wastewater treatment enforced by visible light Sahoo, Dhirendra Kumar, Birendra Sinha, Jaivardhan Ghosh, Subhasis Roy, Susanta Sinha Kaviraj, Bhaskar Sci Rep Article Scalable production of high-quality MoS(2) nanosheets remains challenging for industrial applications and research in basic sciences. N-methyl-2pyrrolidine (NMP) is a commonly used solvent for exfoliation of MoS(2) nanosheets having further disadvantage of slow volatility rate. The present study demonstrates a cost-effective facile chemical route to synthesize few-layer MoS(2) nanosheets using acetone as a solvent and by varying bulk initial concentration of samples to scale up the production in large scale to fulfill the demand for potential applications. In our study, we aim to obtain stable growth of high quality few layer MoS(2) nanosheets by long sonication times. Optical absorption spectra, Raman spectra, size of nanosheets and layer thickness of as-grown MoS(2) nanosheets were found to be matching with those obtained from other synthesis methods. Effective photocatalytic performance of MoS(2) nanosheets without being consumed as a reactant was experimented by decomposing Methylene Blue dye in aqueous solution under irradiation of visible light. This study provides an idea to synthesize low-cost, sustainable and efficient photocatalytic material in large scale for the next generation to control water pollution quite efficiently by protecting the environment from the contamination coming from these dyes. Nature Publishing Group UK 2020-07-01 /pmc/articles/PMC7330046/ /pubmed/32612159 http://dx.doi.org/10.1038/s41598-020-67683-2 Text en © The Author(s) 2020 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Sahoo, Dhirendra
Kumar, Birendra
Sinha, Jaivardhan
Ghosh, Subhasis
Roy, Susanta Sinha
Kaviraj, Bhaskar
Cost effective liquid phase exfoliation of MoS(2) nanosheets and photocatalytic activity for wastewater treatment enforced by visible light
title Cost effective liquid phase exfoliation of MoS(2) nanosheets and photocatalytic activity for wastewater treatment enforced by visible light
title_full Cost effective liquid phase exfoliation of MoS(2) nanosheets and photocatalytic activity for wastewater treatment enforced by visible light
title_fullStr Cost effective liquid phase exfoliation of MoS(2) nanosheets and photocatalytic activity for wastewater treatment enforced by visible light
title_full_unstemmed Cost effective liquid phase exfoliation of MoS(2) nanosheets and photocatalytic activity for wastewater treatment enforced by visible light
title_short Cost effective liquid phase exfoliation of MoS(2) nanosheets and photocatalytic activity for wastewater treatment enforced by visible light
title_sort cost effective liquid phase exfoliation of mos(2) nanosheets and photocatalytic activity for wastewater treatment enforced by visible light
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7330046/
https://www.ncbi.nlm.nih.gov/pubmed/32612159
http://dx.doi.org/10.1038/s41598-020-67683-2
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