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Flexible Type Symmetric Supercapacitor Electrode Fabrication Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from Cow Dung for Renewable Energy Applications
[Image: see text] Porous-activated carbon (PAC) materials have been playing a vital role in meeting the challenges of the ever-increasing demand for alternative clean and sustainable energy technologies. In the present scenario, a facile approach is suggested to produce hierarchical PAC at different...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7330913/ https://www.ncbi.nlm.nih.gov/pubmed/32637776 http://dx.doi.org/10.1021/acsomega.0c00848 |
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author | Rajabathar, Jothi Ramalingam Sivachidambaram, Manoharan Vijaya, J. Judith Al-lohedan, Hamad A. Aldhayan, Dhaifallah M. D. |
author_facet | Rajabathar, Jothi Ramalingam Sivachidambaram, Manoharan Vijaya, J. Judith Al-lohedan, Hamad A. Aldhayan, Dhaifallah M. D. |
author_sort | Rajabathar, Jothi Ramalingam |
collection | PubMed |
description | [Image: see text] Porous-activated carbon (PAC) materials have been playing a vital role in meeting the challenges of the ever-increasing demand for alternative clean and sustainable energy technologies. In the present scenario, a facile approach is suggested to produce hierarchical PAC at different activation temperatures in the range of 600 to 900 °C by using cow dung (CD) waste as a precursor, and H(3)PO(4) is adopted as the nonconventional activating agent to obtain large surface area values. The as-prepared cow dung-based PAC (CDPAC) is graphitic in nature with mixed micro- and mesoporous textures. High-resolution scanning electron microscopy depicts the morphology of CDPAC as nanoporous structures with a uniform arrangement. High-resolution transmission electron microscopy reveals spherical carbon dense nanoparticles with dense tiny spherical carbon particles. N(2) adsorption–desorption isotherms show a very high specific surface area of 2457 m(2)/g for the CDPAC 9 (CD 9) sample with a large pore volume of 1.965 cm(3)/g. Electrochemical measurements of the CD 9 sample show a good specific capacitance (C(s)) of 347 F/g at a lower scan rate (5 mV/s) with improved cyclic stability, which is run up to 5000 cycles at a low current density (0.5 A/g). Hence, we choose an activated carbon prepared at 900 °C to fabricate the modified electrode material. In this regard, a flexible type symmetric supercapacitor device was fabricated, and the electrochemical test results show a supercapacitance value (C(s)) of 208 F/g. |
format | Online Article Text |
id | pubmed-7330913 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-73309132020-07-06 Flexible Type Symmetric Supercapacitor Electrode Fabrication Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from Cow Dung for Renewable Energy Applications Rajabathar, Jothi Ramalingam Sivachidambaram, Manoharan Vijaya, J. Judith Al-lohedan, Hamad A. Aldhayan, Dhaifallah M. D. ACS Omega [Image: see text] Porous-activated carbon (PAC) materials have been playing a vital role in meeting the challenges of the ever-increasing demand for alternative clean and sustainable energy technologies. In the present scenario, a facile approach is suggested to produce hierarchical PAC at different activation temperatures in the range of 600 to 900 °C by using cow dung (CD) waste as a precursor, and H(3)PO(4) is adopted as the nonconventional activating agent to obtain large surface area values. The as-prepared cow dung-based PAC (CDPAC) is graphitic in nature with mixed micro- and mesoporous textures. High-resolution scanning electron microscopy depicts the morphology of CDPAC as nanoporous structures with a uniform arrangement. High-resolution transmission electron microscopy reveals spherical carbon dense nanoparticles with dense tiny spherical carbon particles. N(2) adsorption–desorption isotherms show a very high specific surface area of 2457 m(2)/g for the CDPAC 9 (CD 9) sample with a large pore volume of 1.965 cm(3)/g. Electrochemical measurements of the CD 9 sample show a good specific capacitance (C(s)) of 347 F/g at a lower scan rate (5 mV/s) with improved cyclic stability, which is run up to 5000 cycles at a low current density (0.5 A/g). Hence, we choose an activated carbon prepared at 900 °C to fabricate the modified electrode material. In this regard, a flexible type symmetric supercapacitor device was fabricated, and the electrochemical test results show a supercapacitance value (C(s)) of 208 F/g. American Chemical Society 2020-06-22 /pmc/articles/PMC7330913/ /pubmed/32637776 http://dx.doi.org/10.1021/acsomega.0c00848 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Rajabathar, Jothi Ramalingam Sivachidambaram, Manoharan Vijaya, J. Judith Al-lohedan, Hamad A. Aldhayan, Dhaifallah M. D. Flexible Type Symmetric Supercapacitor Electrode Fabrication Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from Cow Dung for Renewable Energy Applications |
title | Flexible Type Symmetric Supercapacitor Electrode Fabrication
Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from
Cow Dung for Renewable Energy Applications |
title_full | Flexible Type Symmetric Supercapacitor Electrode Fabrication
Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from
Cow Dung for Renewable Energy Applications |
title_fullStr | Flexible Type Symmetric Supercapacitor Electrode Fabrication
Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from
Cow Dung for Renewable Energy Applications |
title_full_unstemmed | Flexible Type Symmetric Supercapacitor Electrode Fabrication
Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from
Cow Dung for Renewable Energy Applications |
title_short | Flexible Type Symmetric Supercapacitor Electrode Fabrication
Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from
Cow Dung for Renewable Energy Applications |
title_sort | flexible type symmetric supercapacitor electrode fabrication
using phosphoric acid-activated carbon nanomaterials derived from
cow dung for renewable energy applications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7330913/ https://www.ncbi.nlm.nih.gov/pubmed/32637776 http://dx.doi.org/10.1021/acsomega.0c00848 |
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