Cargando…

Flexible Type Symmetric Supercapacitor Electrode Fabrication Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from Cow Dung for Renewable Energy Applications

[Image: see text] Porous-activated carbon (PAC) materials have been playing a vital role in meeting the challenges of the ever-increasing demand for alternative clean and sustainable energy technologies. In the present scenario, a facile approach is suggested to produce hierarchical PAC at different...

Descripción completa

Detalles Bibliográficos
Autores principales: Rajabathar, Jothi Ramalingam, Sivachidambaram, Manoharan, Vijaya, J. Judith, Al-lohedan, Hamad A., Aldhayan, Dhaifallah M. D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7330913/
https://www.ncbi.nlm.nih.gov/pubmed/32637776
http://dx.doi.org/10.1021/acsomega.0c00848
_version_ 1783553219068166144
author Rajabathar, Jothi Ramalingam
Sivachidambaram, Manoharan
Vijaya, J. Judith
Al-lohedan, Hamad A.
Aldhayan, Dhaifallah M. D.
author_facet Rajabathar, Jothi Ramalingam
Sivachidambaram, Manoharan
Vijaya, J. Judith
Al-lohedan, Hamad A.
Aldhayan, Dhaifallah M. D.
author_sort Rajabathar, Jothi Ramalingam
collection PubMed
description [Image: see text] Porous-activated carbon (PAC) materials have been playing a vital role in meeting the challenges of the ever-increasing demand for alternative clean and sustainable energy technologies. In the present scenario, a facile approach is suggested to produce hierarchical PAC at different activation temperatures in the range of 600 to 900 °C by using cow dung (CD) waste as a precursor, and H(3)PO(4) is adopted as the nonconventional activating agent to obtain large surface area values. The as-prepared cow dung-based PAC (CDPAC) is graphitic in nature with mixed micro- and mesoporous textures. High-resolution scanning electron microscopy depicts the morphology of CDPAC as nanoporous structures with a uniform arrangement. High-resolution transmission electron microscopy reveals spherical carbon dense nanoparticles with dense tiny spherical carbon particles. N(2) adsorption–desorption isotherms show a very high specific surface area of 2457 m(2)/g for the CDPAC 9 (CD 9) sample with a large pore volume of 1.965 cm(3)/g. Electrochemical measurements of the CD 9 sample show a good specific capacitance (C(s)) of 347 F/g at a lower scan rate (5 mV/s) with improved cyclic stability, which is run up to 5000 cycles at a low current density (0.5 A/g). Hence, we choose an activated carbon prepared at 900 °C to fabricate the modified electrode material. In this regard, a flexible type symmetric supercapacitor device was fabricated, and the electrochemical test results show a supercapacitance value (C(s)) of 208 F/g.
format Online
Article
Text
id pubmed-7330913
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-73309132020-07-06 Flexible Type Symmetric Supercapacitor Electrode Fabrication Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from Cow Dung for Renewable Energy Applications Rajabathar, Jothi Ramalingam Sivachidambaram, Manoharan Vijaya, J. Judith Al-lohedan, Hamad A. Aldhayan, Dhaifallah M. D. ACS Omega [Image: see text] Porous-activated carbon (PAC) materials have been playing a vital role in meeting the challenges of the ever-increasing demand for alternative clean and sustainable energy technologies. In the present scenario, a facile approach is suggested to produce hierarchical PAC at different activation temperatures in the range of 600 to 900 °C by using cow dung (CD) waste as a precursor, and H(3)PO(4) is adopted as the nonconventional activating agent to obtain large surface area values. The as-prepared cow dung-based PAC (CDPAC) is graphitic in nature with mixed micro- and mesoporous textures. High-resolution scanning electron microscopy depicts the morphology of CDPAC as nanoporous structures with a uniform arrangement. High-resolution transmission electron microscopy reveals spherical carbon dense nanoparticles with dense tiny spherical carbon particles. N(2) adsorption–desorption isotherms show a very high specific surface area of 2457 m(2)/g for the CDPAC 9 (CD 9) sample with a large pore volume of 1.965 cm(3)/g. Electrochemical measurements of the CD 9 sample show a good specific capacitance (C(s)) of 347 F/g at a lower scan rate (5 mV/s) with improved cyclic stability, which is run up to 5000 cycles at a low current density (0.5 A/g). Hence, we choose an activated carbon prepared at 900 °C to fabricate the modified electrode material. In this regard, a flexible type symmetric supercapacitor device was fabricated, and the electrochemical test results show a supercapacitance value (C(s)) of 208 F/g. American Chemical Society 2020-06-22 /pmc/articles/PMC7330913/ /pubmed/32637776 http://dx.doi.org/10.1021/acsomega.0c00848 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Rajabathar, Jothi Ramalingam
Sivachidambaram, Manoharan
Vijaya, J. Judith
Al-lohedan, Hamad A.
Aldhayan, Dhaifallah M. D.
Flexible Type Symmetric Supercapacitor Electrode Fabrication Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from Cow Dung for Renewable Energy Applications
title Flexible Type Symmetric Supercapacitor Electrode Fabrication Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from Cow Dung for Renewable Energy Applications
title_full Flexible Type Symmetric Supercapacitor Electrode Fabrication Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from Cow Dung for Renewable Energy Applications
title_fullStr Flexible Type Symmetric Supercapacitor Electrode Fabrication Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from Cow Dung for Renewable Energy Applications
title_full_unstemmed Flexible Type Symmetric Supercapacitor Electrode Fabrication Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from Cow Dung for Renewable Energy Applications
title_short Flexible Type Symmetric Supercapacitor Electrode Fabrication Using Phosphoric Acid-Activated Carbon Nanomaterials Derived from Cow Dung for Renewable Energy Applications
title_sort flexible type symmetric supercapacitor electrode fabrication using phosphoric acid-activated carbon nanomaterials derived from cow dung for renewable energy applications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7330913/
https://www.ncbi.nlm.nih.gov/pubmed/32637776
http://dx.doi.org/10.1021/acsomega.0c00848
work_keys_str_mv AT rajabatharjothiramalingam flexibletypesymmetricsupercapacitorelectrodefabricationusingphosphoricacidactivatedcarbonnanomaterialsderivedfromcowdungforrenewableenergyapplications
AT sivachidambarammanoharan flexibletypesymmetricsupercapacitorelectrodefabricationusingphosphoricacidactivatedcarbonnanomaterialsderivedfromcowdungforrenewableenergyapplications
AT vijayajjudith flexibletypesymmetricsupercapacitorelectrodefabricationusingphosphoricacidactivatedcarbonnanomaterialsderivedfromcowdungforrenewableenergyapplications
AT allohedanhamada flexibletypesymmetricsupercapacitorelectrodefabricationusingphosphoricacidactivatedcarbonnanomaterialsderivedfromcowdungforrenewableenergyapplications
AT aldhayandhaifallahmd flexibletypesymmetricsupercapacitorelectrodefabricationusingphosphoricacidactivatedcarbonnanomaterialsderivedfromcowdungforrenewableenergyapplications