Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-chloro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline

The title compound, C(16)H(14)Cl(3)N(3), comprises three mol­ecules of similar shape in the asymmetric unit. The crystal cohesion is ensured by inter­molecular C—H⋯N and C—H⋯Cl hydrogen bonds in addition to C—Cl⋯π inter­actions. Hirshfeld surface analysis and two-dimensional fingerprint plots reveal...

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Autores principales: Atioğlu, Zeliha, Akkurt, Mehmet, Shikhaliyev, Namiq Q., Mukhtarova, Sevinc H., Suleymanova, Gulnar T., Toze, Flavien A. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336775/
https://www.ncbi.nlm.nih.gov/pubmed/32695447
http://dx.doi.org/10.1107/S2056989020007549
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author Atioğlu, Zeliha
Akkurt, Mehmet
Shikhaliyev, Namiq Q.
Mukhtarova, Sevinc H.
Suleymanova, Gulnar T.
Toze, Flavien A. A.
author_facet Atioğlu, Zeliha
Akkurt, Mehmet
Shikhaliyev, Namiq Q.
Mukhtarova, Sevinc H.
Suleymanova, Gulnar T.
Toze, Flavien A. A.
author_sort Atioğlu, Zeliha
collection PubMed
description The title compound, C(16)H(14)Cl(3)N(3), comprises three mol­ecules of similar shape in the asymmetric unit. The crystal cohesion is ensured by inter­molecular C—H⋯N and C—H⋯Cl hydrogen bonds in addition to C—Cl⋯π inter­actions. Hirshfeld surface analysis and two-dimensional fingerprint plots reveal that Cl⋯H/H⋯Cl (33.6%), H⋯H (27.9%) and C⋯H/H⋯C (17.6%) are the most important contributors towards the crystal packing.
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spelling pubmed-73367752020-07-20 Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-chloro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline Atioğlu, Zeliha Akkurt, Mehmet Shikhaliyev, Namiq Q. Mukhtarova, Sevinc H. Suleymanova, Gulnar T. Toze, Flavien A. A. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(16)H(14)Cl(3)N(3), comprises three mol­ecules of similar shape in the asymmetric unit. The crystal cohesion is ensured by inter­molecular C—H⋯N and C—H⋯Cl hydrogen bonds in addition to C—Cl⋯π inter­actions. Hirshfeld surface analysis and two-dimensional fingerprint plots reveal that Cl⋯H/H⋯Cl (33.6%), H⋯H (27.9%) and C⋯H/H⋯C (17.6%) are the most important contributors towards the crystal packing. International Union of Crystallography 2020-06-09 /pmc/articles/PMC7336775/ /pubmed/32695447 http://dx.doi.org/10.1107/S2056989020007549 Text en © Atioğlu et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Atioğlu, Zeliha
Akkurt, Mehmet
Shikhaliyev, Namiq Q.
Mukhtarova, Sevinc H.
Suleymanova, Gulnar T.
Toze, Flavien A. A.
Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-chloro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline
title Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-chloro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline
title_full Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-chloro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline
title_fullStr Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-chloro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-chloro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline
title_short Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-chloro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline
title_sort crystal structure and hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(e)-(4-chloro­phen­yl)diazen­yl]ethen­yl}-n,n-di­methyl­aniline
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336775/
https://www.ncbi.nlm.nih.gov/pubmed/32695447
http://dx.doi.org/10.1107/S2056989020007549
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