Crystal structure of SrCo(4)(OH)(PO(4))(3), a new hy­droxy­phosphate

Single crystals of strontium tetra­cobalt tris­(orthophosphate) hydroxide, SrCo(4)(OH)(PO(4))(3), were grown serendipitously under hydro­thermal conditions at 473 K. The crystal structure consists of undulating chains of edge-sharing [CoO(6)] octa­hedra that are linked into (010) layers by common ve...

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Autores principales: Cherif, Fatima-Zahra, Taibi, Mhamed, Boukhari, Ali, Aride, Jilali, Assani, Abderrazzak, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336777/
https://www.ncbi.nlm.nih.gov/pubmed/32695445
http://dx.doi.org/10.1107/S2056989020007331
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author Cherif, Fatima-Zahra
Taibi, Mhamed
Boukhari, Ali
Aride, Jilali
Assani, Abderrazzak
Saadi, Mohamed
El Ammari, Lahcen
author_facet Cherif, Fatima-Zahra
Taibi, Mhamed
Boukhari, Ali
Aride, Jilali
Assani, Abderrazzak
Saadi, Mohamed
El Ammari, Lahcen
author_sort Cherif, Fatima-Zahra
collection PubMed
description Single crystals of strontium tetra­cobalt tris­(orthophosphate) hydroxide, SrCo(4)(OH)(PO(4))(3), were grown serendipitously under hydro­thermal conditions at 473 K. The crystal structure consists of undulating chains of edge-sharing [CoO(6)] octa­hedra that are linked into (010) layers by common vertices between chains. Adjacent layers are linked along [010] into a framework structure by tetra­hedral [CoO(4)] units and by PO(4) tetra­hedra. The framework delimits channels extending along [100] in which the eleven-coordinate strontium cations are situated. Bifurcated O—H⋯O hydrogen bonds of weak strengths consolidate the crystal packing. The title compound was also characterized by infrared spectroscopy.
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spelling pubmed-73367772020-07-20 Crystal structure of SrCo(4)(OH)(PO(4))(3), a new hy­droxy­phosphate Cherif, Fatima-Zahra Taibi, Mhamed Boukhari, Ali Aride, Jilali Assani, Abderrazzak Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr E Crystallogr Commun Research Communications Single crystals of strontium tetra­cobalt tris­(orthophosphate) hydroxide, SrCo(4)(OH)(PO(4))(3), were grown serendipitously under hydro­thermal conditions at 473 K. The crystal structure consists of undulating chains of edge-sharing [CoO(6)] octa­hedra that are linked into (010) layers by common vertices between chains. Adjacent layers are linked along [010] into a framework structure by tetra­hedral [CoO(4)] units and by PO(4) tetra­hedra. The framework delimits channels extending along [100] in which the eleven-coordinate strontium cations are situated. Bifurcated O—H⋯O hydrogen bonds of weak strengths consolidate the crystal packing. The title compound was also characterized by infrared spectroscopy. International Union of Crystallography 2020-06-05 /pmc/articles/PMC7336777/ /pubmed/32695445 http://dx.doi.org/10.1107/S2056989020007331 Text en © Cherif et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Cherif, Fatima-Zahra
Taibi, Mhamed
Boukhari, Ali
Aride, Jilali
Assani, Abderrazzak
Saadi, Mohamed
El Ammari, Lahcen
Crystal structure of SrCo(4)(OH)(PO(4))(3), a new hy­droxy­phosphate
title Crystal structure of SrCo(4)(OH)(PO(4))(3), a new hy­droxy­phosphate
title_full Crystal structure of SrCo(4)(OH)(PO(4))(3), a new hy­droxy­phosphate
title_fullStr Crystal structure of SrCo(4)(OH)(PO(4))(3), a new hy­droxy­phosphate
title_full_unstemmed Crystal structure of SrCo(4)(OH)(PO(4))(3), a new hy­droxy­phosphate
title_short Crystal structure of SrCo(4)(OH)(PO(4))(3), a new hy­droxy­phosphate
title_sort crystal structure of srco(4)(oh)(po(4))(3), a new hy­droxy­phosphate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336777/
https://www.ncbi.nlm.nih.gov/pubmed/32695445
http://dx.doi.org/10.1107/S2056989020007331
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