Synthesis and crystal structure of [Zn(6)Br(4)(C(9)H(18)NO)(4)(OH)(4)]·2C(3)H(6)O(2)

The complete mol­ecule of the hexa­metallic title complex, namely, tetra­bromido­tetra-μ-hydroxido-hexa­kis­[μ-2-methyl-3-(pyrrolidin-1-yl)propan-2-olato]hexa­zinc(II) acetone disolvate, [Zn(6)Br(4)(C(9)H(18)NO)(4)(OH)(4)]·2C(3)H(6)O(2), is generated by a crystallographic centre of symmetry. Two of...

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Autores principales: Scheel, Rebecca, Brieger, Lukas, Louven, Kathrin, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336778/
https://www.ncbi.nlm.nih.gov/pubmed/32695440
http://dx.doi.org/10.1107/S2056989020007100
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author Scheel, Rebecca
Brieger, Lukas
Louven, Kathrin
Strohmann, Carsten
author_facet Scheel, Rebecca
Brieger, Lukas
Louven, Kathrin
Strohmann, Carsten
author_sort Scheel, Rebecca
collection PubMed
description The complete mol­ecule of the hexa­metallic title complex, namely, tetra­bromido­tetra-μ-hydroxido-hexa­kis­[μ-2-methyl-3-(pyrrolidin-1-yl)propan-2-olato]hexa­zinc(II) acetone disolvate, [Zn(6)Br(4)(C(9)H(18)NO)(4)(OH)(4)]·2C(3)H(6)O(2), is generated by a crystallographic centre of symmetry. Two of the unique zinc atoms adopt distorted ZnO(2)NBr tetra­hedral coordination geometries and the other adopts a ZnO(3)N tetra­hedral arrangement. Both unique alkoxide ligands are N,O-chelating and both hydroxide ions are μ(2) bridging. The crystal structure displays an O—H⋯O hydrogen bond between a μ(2)-OH group and an acetone solvent mol­ecule. The Hirshfeld surface has been calculated and is described.
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spelling pubmed-73367782020-07-20 Synthesis and crystal structure of [Zn(6)Br(4)(C(9)H(18)NO)(4)(OH)(4)]·2C(3)H(6)O(2) Scheel, Rebecca Brieger, Lukas Louven, Kathrin Strohmann, Carsten Acta Crystallogr E Crystallogr Commun Research Communications The complete mol­ecule of the hexa­metallic title complex, namely, tetra­bromido­tetra-μ-hydroxido-hexa­kis­[μ-2-methyl-3-(pyrrolidin-1-yl)propan-2-olato]hexa­zinc(II) acetone disolvate, [Zn(6)Br(4)(C(9)H(18)NO)(4)(OH)(4)]·2C(3)H(6)O(2), is generated by a crystallographic centre of symmetry. Two of the unique zinc atoms adopt distorted ZnO(2)NBr tetra­hedral coordination geometries and the other adopts a ZnO(3)N tetra­hedral arrangement. Both unique alkoxide ligands are N,O-chelating and both hydroxide ions are μ(2) bridging. The crystal structure displays an O—H⋯O hydrogen bond between a μ(2)-OH group and an acetone solvent mol­ecule. The Hirshfeld surface has been calculated and is described. International Union of Crystallography 2020-06-02 /pmc/articles/PMC7336778/ /pubmed/32695440 http://dx.doi.org/10.1107/S2056989020007100 Text en © Scheel et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Scheel, Rebecca
Brieger, Lukas
Louven, Kathrin
Strohmann, Carsten
Synthesis and crystal structure of [Zn(6)Br(4)(C(9)H(18)NO)(4)(OH)(4)]·2C(3)H(6)O(2)
title Synthesis and crystal structure of [Zn(6)Br(4)(C(9)H(18)NO)(4)(OH)(4)]·2C(3)H(6)O(2)
title_full Synthesis and crystal structure of [Zn(6)Br(4)(C(9)H(18)NO)(4)(OH)(4)]·2C(3)H(6)O(2)
title_fullStr Synthesis and crystal structure of [Zn(6)Br(4)(C(9)H(18)NO)(4)(OH)(4)]·2C(3)H(6)O(2)
title_full_unstemmed Synthesis and crystal structure of [Zn(6)Br(4)(C(9)H(18)NO)(4)(OH)(4)]·2C(3)H(6)O(2)
title_short Synthesis and crystal structure of [Zn(6)Br(4)(C(9)H(18)NO)(4)(OH)(4)]·2C(3)H(6)O(2)
title_sort synthesis and crystal structure of [zn(6)br(4)(c(9)h(18)no)(4)(oh)(4)]·2c(3)h(6)o(2)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336778/
https://www.ncbi.nlm.nih.gov/pubmed/32695440
http://dx.doi.org/10.1107/S2056989020007100
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AT louvenkathrin synthesisandcrystalstructureofzn6br4c9h18no4oh42c3h6o2
AT strohmanncarsten synthesisandcrystalstructureofzn6br4c9h18no4oh42c3h6o2

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