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Comparison of two Mn(IV)Mn(IV)-bis-μ-oxo complexes {[Mn(IV)(N(4)(6-Me-DPEN))](2)(μ-O)(2)}(2+) and {[Mn(IV)(N(4)(6-Me-DPPN))](2)(μ-O)(2)}(2+)
The addition of tert-butyl hydroperoxide ((t)BuOOH) to two structurally related Mn(II) complexes containing N,N-bis(6-methyl-2-pyridylmethyl)ethane-1,2-diamine (6-Me-DPEN) and N,N-bis(6-methyl-2-pyridylmethyl)propane-1,2-diamine (6-Me-DPPN) results in the formation of high-valent bis-oxo co...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336796/ https://www.ncbi.nlm.nih.gov/pubmed/32695449 http://dx.doi.org/10.1107/S2056989020004557 |