Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator

Exceptionally large crystals of posnjakite, Cu(4)SO(4)(OH)(6)(H(2)O), formed during corrosion of a Swagelock(tm) Snubber copper gasket within the MX1 beamline at the ANSTO-Melbourne, Australian Synchrotron. The crystal structure was solved using synchrotron radiation to R (1) = 0.029 and revealed a...

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Autores principales: Mills, Stuart, Aishima, Jun, Aragao, David, Caradoc-Davies, Tom Tudor, Cowieson, Nathan, Gee, Christine L., Ericsson, Daniel, Harrop, Stephen, Panjikar, Santosh, Smith, Kate Mary Louise, Riboldi-Tunnicliffe, Alan, Williamson, Rachel, Price, Jason Roy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336798/
https://www.ncbi.nlm.nih.gov/pubmed/32695467
http://dx.doi.org/10.1107/S2056989020008099
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author Mills, Stuart
Aishima, Jun
Aragao, David
Caradoc-Davies, Tom Tudor
Cowieson, Nathan
Gee, Christine L.
Ericsson, Daniel
Harrop, Stephen
Panjikar, Santosh
Smith, Kate Mary Louise
Riboldi-Tunnicliffe, Alan
Williamson, Rachel
Price, Jason Roy
author_facet Mills, Stuart
Aishima, Jun
Aragao, David
Caradoc-Davies, Tom Tudor
Cowieson, Nathan
Gee, Christine L.
Ericsson, Daniel
Harrop, Stephen
Panjikar, Santosh
Smith, Kate Mary Louise
Riboldi-Tunnicliffe, Alan
Williamson, Rachel
Price, Jason Roy
author_sort Mills, Stuart
collection PubMed
description Exceptionally large crystals of posnjakite, Cu(4)SO(4)(OH)(6)(H(2)O), formed during corrosion of a Swagelock(tm) Snubber copper gasket within the MX1 beamline at the ANSTO-Melbourne, Australian Synchrotron. The crystal structure was solved using synchrotron radiation to R (1) = 0.029 and revealed a structure based upon [Cu(4)(OH)(6)(H(2)O)O] sheets, which contain Jahn–Teller-distorted Cu octa­hedra. The sulfate tetra­hedra are bonded to one side of the sheet via corner sharing and linked to successive sheets via extensive hydrogen bonds. The sulfate tetra­hedra are split and rotated, which enables additional hydrogen bonds.
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spelling pubmed-73367982020-07-20 Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator Mills, Stuart Aishima, Jun Aragao, David Caradoc-Davies, Tom Tudor Cowieson, Nathan Gee, Christine L. Ericsson, Daniel Harrop, Stephen Panjikar, Santosh Smith, Kate Mary Louise Riboldi-Tunnicliffe, Alan Williamson, Rachel Price, Jason Roy Acta Crystallogr E Crystallogr Commun Research Communications Exceptionally large crystals of posnjakite, Cu(4)SO(4)(OH)(6)(H(2)O), formed during corrosion of a Swagelock(tm) Snubber copper gasket within the MX1 beamline at the ANSTO-Melbourne, Australian Synchrotron. The crystal structure was solved using synchrotron radiation to R (1) = 0.029 and revealed a structure based upon [Cu(4)(OH)(6)(H(2)O)O] sheets, which contain Jahn–Teller-distorted Cu octa­hedra. The sulfate tetra­hedra are bonded to one side of the sheet via corner sharing and linked to successive sheets via extensive hydrogen bonds. The sulfate tetra­hedra are split and rotated, which enables additional hydrogen bonds. International Union of Crystallography 2020-06-26 /pmc/articles/PMC7336798/ /pubmed/32695467 http://dx.doi.org/10.1107/S2056989020008099 Text en © Mills et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Mills, Stuart
Aishima, Jun
Aragao, David
Caradoc-Davies, Tom Tudor
Cowieson, Nathan
Gee, Christine L.
Ericsson, Daniel
Harrop, Stephen
Panjikar, Santosh
Smith, Kate Mary Louise
Riboldi-Tunnicliffe, Alan
Williamson, Rachel
Price, Jason Roy
Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator
title Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator
title_full Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator
title_fullStr Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator
title_full_unstemmed Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator
title_short Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator
title_sort crystal structure of posnjakite formed in the first crystal water-cooling line of the ansto melbourne australian synchrotron mx1 double crystal monochromator
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336798/
https://www.ncbi.nlm.nih.gov/pubmed/32695467
http://dx.doi.org/10.1107/S2056989020008099
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