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Crystal structure of N,N-diisopropyl-4-methyl­benzene­sulfonamide

The synthesis of the title compound, C(13)H(21)NO(2)S, is reported here along with its crystal structure. This compound crystallizes with two mol­ecules in the asymmetric unit. The sulfonamide functional group of this structure features S=O bond lengths ranging from 1.433 (3) to 1.439 (3) Å, S—C bon...

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Detalles Bibliográficos
Autores principales: Stenfors, Brock A., Staples, Richard J., Biros, Shannon M., Ngassa, Felix N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336799/
https://www.ncbi.nlm.nih.gov/pubmed/32695444
http://dx.doi.org/10.1107/S2056989020007185
Descripción
Sumario:The synthesis of the title compound, C(13)H(21)NO(2)S, is reported here along with its crystal structure. This compound crystallizes with two mol­ecules in the asymmetric unit. The sulfonamide functional group of this structure features S=O bond lengths ranging from 1.433 (3) to 1.439 (3) Å, S—C bond lengths of 1.777 (3) and 1.773 (4) Å, and S—N bond lengths of 1.622 (3) and 1.624 (3) Å. When viewing the mol­ecules down the S—N bond, the isopropyl groups are gauche to the aromatic ring. On each mol­ecule, two methyl hydrogen atoms of one isopropyl group are engaged in intra­molecular C—H⋯O hydrogen bonds with a nearby sulfonamide oxygen atom. Inter­molecular C—H⋯O hydrogen bonds and C—H⋯π inter­actions link mol­ecules of the title compound in the solid state.