Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodo­phen­yl)imino]­meth­yl}-4-nitro­phenol

The title compound, C(13)H(9)IN(2)O(3), was synthesized by a condensation reaction between 2-hy­droxy-5-nitro­benzaldehyde and 4-iodo­aniline, and crystallizes in the ortho­rhom­bic space group Pna2(1). The 4-iodo­benzene ring is inclined to the phenol ring by a dihedral angle of 39.1 (2)°. The conf...

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Autores principales: Faizi, Md. Serajul Haque, Alagöz, Tenzile, Ahmed, Ruby, Cinar, Emine Berrin, Agar, Erbil, Dege, Necmi, Mashrai, Ashraf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336806/
https://www.ncbi.nlm.nih.gov/pubmed/32695470
http://dx.doi.org/10.1107/S2056989020008191
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author Faizi, Md. Serajul Haque
Alagöz, Tenzile
Ahmed, Ruby
Cinar, Emine Berrin
Agar, Erbil
Dege, Necmi
Mashrai, Ashraf
author_facet Faizi, Md. Serajul Haque
Alagöz, Tenzile
Ahmed, Ruby
Cinar, Emine Berrin
Agar, Erbil
Dege, Necmi
Mashrai, Ashraf
author_sort Faizi, Md. Serajul Haque
collection PubMed
description The title compound, C(13)H(9)IN(2)O(3), was synthesized by a condensation reaction between 2-hy­droxy-5-nitro­benzaldehyde and 4-iodo­aniline, and crystallizes in the ortho­rhom­bic space group Pna2(1). The 4-iodo­benzene ring is inclined to the phenol ring by a dihedral angle of 39.1 (2)°. The configuration about the C=N double bond is E. The crystal structure features C—H⋯O hydrogen-bonding inter­actions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the packing arrangement are O⋯H/H⋯O (26.9%) and H⋯H (22.0%) inter­actions.
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spelling pubmed-73368062020-07-20 Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodo­phen­yl)imino]­meth­yl}-4-nitro­phenol Faizi, Md. Serajul Haque Alagöz, Tenzile Ahmed, Ruby Cinar, Emine Berrin Agar, Erbil Dege, Necmi Mashrai, Ashraf Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(13)H(9)IN(2)O(3), was synthesized by a condensation reaction between 2-hy­droxy-5-nitro­benzaldehyde and 4-iodo­aniline, and crystallizes in the ortho­rhom­bic space group Pna2(1). The 4-iodo­benzene ring is inclined to the phenol ring by a dihedral angle of 39.1 (2)°. The configuration about the C=N double bond is E. The crystal structure features C—H⋯O hydrogen-bonding inter­actions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the packing arrangement are O⋯H/H⋯O (26.9%) and H⋯H (22.0%) inter­actions. International Union of Crystallography 2020-06-26 /pmc/articles/PMC7336806/ /pubmed/32695470 http://dx.doi.org/10.1107/S2056989020008191 Text en © Faizi et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Faizi, Md. Serajul Haque
Alagöz, Tenzile
Ahmed, Ruby
Cinar, Emine Berrin
Agar, Erbil
Dege, Necmi
Mashrai, Ashraf
Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodo­phen­yl)imino]­meth­yl}-4-nitro­phenol
title Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodo­phen­yl)imino]­meth­yl}-4-nitro­phenol
title_full Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodo­phen­yl)imino]­meth­yl}-4-nitro­phenol
title_fullStr Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodo­phen­yl)imino]­meth­yl}-4-nitro­phenol
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodo­phen­yl)imino]­meth­yl}-4-nitro­phenol
title_short Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodo­phen­yl)imino]­meth­yl}-4-nitro­phenol
title_sort crystal structure and hirshfeld surface analysis of 2-{[(4-iodo­phen­yl)imino]­meth­yl}-4-nitro­phenol
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336806/
https://www.ncbi.nlm.nih.gov/pubmed/32695470
http://dx.doi.org/10.1107/S2056989020008191
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