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Cross-Metathesis of Methallyl Halides: Concise Enantioselective Formal Total Synthesis of (–)-Presphaerene

The cross-metathesis (CM) of methallyl halides catalyzed using four different ruthenium-based complexes—Grubbs catalyst, Grubbs second-generation catalyst, Hoveyda-Grubbs second-generation catalyst, and Stewart–Grubbs catalyst—was investigated. When methallyl chloride or bromide was reacted with a m...

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Detalles Bibliográficos
Autores principales:	Mandava, Suresh, Koo, Jaun, Hwang, Jungjoong, Nallapaneni, Hari Krishna, Park, Haeil, Lee, Jongkook
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Frontiers Media S.A. 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7344242/ https://www.ncbi.nlm.nih.gov/pubmed/32714895 http://dx.doi.org/10.3389/fchem.2020.00494

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