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Quaternization of Composite Algal/PEI Beads for Enhanced Uranium Sorption—Application to Ore Acidic Leachate

The necessity to recover uranium from dilute solutions (for environmental/safety and resource management) is driving research towards developing new sorbents. This study focuses on the enhancement of U(VI) sorption properties of composite algal/Polyethylenimine beads through the quaternization of th...

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Autores principales: Hamza, Mohammed F., Mubark, Amal E., Wei, Yuezou, Vincent, Thierry, Guibal, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7345210/
https://www.ncbi.nlm.nih.gov/pubmed/32235683
http://dx.doi.org/10.3390/gels6020012
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author Hamza, Mohammed F.
Mubark, Amal E.
Wei, Yuezou
Vincent, Thierry
Guibal, Eric
author_facet Hamza, Mohammed F.
Mubark, Amal E.
Wei, Yuezou
Vincent, Thierry
Guibal, Eric
author_sort Hamza, Mohammed F.
collection PubMed
description The necessity to recover uranium from dilute solutions (for environmental/safety and resource management) is driving research towards developing new sorbents. This study focuses on the enhancement of U(VI) sorption properties of composite algal/Polyethylenimine beads through the quaternization of the support (by reaction with glycidyltrimethylammonium chloride). The sorbent is fully characterized by FTIR, XPS for confirming the contribution of protonated amine and quaternary ammonium groups on U(VI) binding (with possible contribution of hydroxyl and carboxyl groups, depending on the pH). The sorption properties are investigated in batch with reference to pH effect (optimum value: pH 4), uptake kinetics (equilibrium: 40 min) and sorption isotherms (maximum sorption capacity: 0.86 mmol U g(−1)). Metal desorption (with 0.5 M NaCl/0.5 M HCl) is highly efficient and the sorbent can be reused for five cycles with limited decrease in performance. The sorbent is successfully applied to the selective recovery of U(VI) from acidic leachate of uranium ore, after pre-treatment (cementation of copper, precipitation of rare earth elements with oxalate, and precipitation of iron). A pure yellow cake is obtained after precipitation of the eluate.
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spelling pubmed-73452102020-07-09 Quaternization of Composite Algal/PEI Beads for Enhanced Uranium Sorption—Application to Ore Acidic Leachate Hamza, Mohammed F. Mubark, Amal E. Wei, Yuezou Vincent, Thierry Guibal, Eric Gels Article The necessity to recover uranium from dilute solutions (for environmental/safety and resource management) is driving research towards developing new sorbents. This study focuses on the enhancement of U(VI) sorption properties of composite algal/Polyethylenimine beads through the quaternization of the support (by reaction with glycidyltrimethylammonium chloride). The sorbent is fully characterized by FTIR, XPS for confirming the contribution of protonated amine and quaternary ammonium groups on U(VI) binding (with possible contribution of hydroxyl and carboxyl groups, depending on the pH). The sorption properties are investigated in batch with reference to pH effect (optimum value: pH 4), uptake kinetics (equilibrium: 40 min) and sorption isotherms (maximum sorption capacity: 0.86 mmol U g(−1)). Metal desorption (with 0.5 M NaCl/0.5 M HCl) is highly efficient and the sorbent can be reused for five cycles with limited decrease in performance. The sorbent is successfully applied to the selective recovery of U(VI) from acidic leachate of uranium ore, after pre-treatment (cementation of copper, precipitation of rare earth elements with oxalate, and precipitation of iron). A pure yellow cake is obtained after precipitation of the eluate. MDPI 2020-03-30 /pmc/articles/PMC7345210/ /pubmed/32235683 http://dx.doi.org/10.3390/gels6020012 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Hamza, Mohammed F.
Mubark, Amal E.
Wei, Yuezou
Vincent, Thierry
Guibal, Eric
Quaternization of Composite Algal/PEI Beads for Enhanced Uranium Sorption—Application to Ore Acidic Leachate
title Quaternization of Composite Algal/PEI Beads for Enhanced Uranium Sorption—Application to Ore Acidic Leachate
title_full Quaternization of Composite Algal/PEI Beads for Enhanced Uranium Sorption—Application to Ore Acidic Leachate
title_fullStr Quaternization of Composite Algal/PEI Beads for Enhanced Uranium Sorption—Application to Ore Acidic Leachate
title_full_unstemmed Quaternization of Composite Algal/PEI Beads for Enhanced Uranium Sorption—Application to Ore Acidic Leachate
title_short Quaternization of Composite Algal/PEI Beads for Enhanced Uranium Sorption—Application to Ore Acidic Leachate
title_sort quaternization of composite algal/pei beads for enhanced uranium sorption—application to ore acidic leachate
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7345210/
https://www.ncbi.nlm.nih.gov/pubmed/32235683
http://dx.doi.org/10.3390/gels6020012
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