Cargando…

Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties

Coordination polymers are constructed from metal ions and bridging ligands, linking them into solid-state structures extending in one (1D), two (2D) or three dimensions (3D). Two- and three-dimensional coordination polymers with potential voids are often referred to as metal-organic frameworks (MOFs...

Descripción completa

Detalles Bibliográficos
Autores principales: Kuznetsova, Anastasia, Matveevskaya, Vladislava, Pavlov, Dmitry, Yakunenkov, Andrei, Potapov, Andrei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7345804/
https://www.ncbi.nlm.nih.gov/pubmed/32545737
http://dx.doi.org/10.3390/ma13122699
_version_ 1783556268923813888
author Kuznetsova, Anastasia
Matveevskaya, Vladislava
Pavlov, Dmitry
Yakunenkov, Andrei
Potapov, Andrei
author_facet Kuznetsova, Anastasia
Matveevskaya, Vladislava
Pavlov, Dmitry
Yakunenkov, Andrei
Potapov, Andrei
author_sort Kuznetsova, Anastasia
collection PubMed
description Coordination polymers are constructed from metal ions and bridging ligands, linking them into solid-state structures extending in one (1D), two (2D) or three dimensions (3D). Two- and three-dimensional coordination polymers with potential voids are often referred to as metal-organic frameworks (MOFs) or porous coordination polymers. Luminescence is an important property of coordination polymers, often playing a key role in their applications. Photophysical properties of the coordination polymers can be associated with intraligand, metal-centered, guest-centered, metal-to-ligand and ligand-to-metal electron transitions. In recent years, a rapid growth of publications devoted to luminescent or fluorescent coordination polymers can be observed. In this review the use of fluorescent ligands, namely, 4,4′-stilbenedicarboxylic acid, 1,3,4-oxadiazole, thiazole, 2,1,3-benzothiadiazole, terpyridine and carbazole derivatives, naphthalene diimides, 4,4′,4′′-nitrilotribenzoic acid, ruthenium(II) and iridium(III) complexes, boron-dipyrromethene (BODIPY) derivatives, porphyrins, for the construction of coordination polymers are surveyed. Applications of such coordination polymers based on their photophysical properties will be discussed. The review covers the literature published before April 2020.
format Online
Article
Text
id pubmed-7345804
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-73458042020-07-09 Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties Kuznetsova, Anastasia Matveevskaya, Vladislava Pavlov, Dmitry Yakunenkov, Andrei Potapov, Andrei Materials (Basel) Review Coordination polymers are constructed from metal ions and bridging ligands, linking them into solid-state structures extending in one (1D), two (2D) or three dimensions (3D). Two- and three-dimensional coordination polymers with potential voids are often referred to as metal-organic frameworks (MOFs) or porous coordination polymers. Luminescence is an important property of coordination polymers, often playing a key role in their applications. Photophysical properties of the coordination polymers can be associated with intraligand, metal-centered, guest-centered, metal-to-ligand and ligand-to-metal electron transitions. In recent years, a rapid growth of publications devoted to luminescent or fluorescent coordination polymers can be observed. In this review the use of fluorescent ligands, namely, 4,4′-stilbenedicarboxylic acid, 1,3,4-oxadiazole, thiazole, 2,1,3-benzothiadiazole, terpyridine and carbazole derivatives, naphthalene diimides, 4,4′,4′′-nitrilotribenzoic acid, ruthenium(II) and iridium(III) complexes, boron-dipyrromethene (BODIPY) derivatives, porphyrins, for the construction of coordination polymers are surveyed. Applications of such coordination polymers based on their photophysical properties will be discussed. The review covers the literature published before April 2020. MDPI 2020-06-13 /pmc/articles/PMC7345804/ /pubmed/32545737 http://dx.doi.org/10.3390/ma13122699 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Kuznetsova, Anastasia
Matveevskaya, Vladislava
Pavlov, Dmitry
Yakunenkov, Andrei
Potapov, Andrei
Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties
title Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties
title_full Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties
title_fullStr Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties
title_full_unstemmed Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties
title_short Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties
title_sort coordination polymers based on highly emissive ligands: synthesis and functional properties
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7345804/
https://www.ncbi.nlm.nih.gov/pubmed/32545737
http://dx.doi.org/10.3390/ma13122699
work_keys_str_mv AT kuznetsovaanastasia coordinationpolymersbasedonhighlyemissiveligandssynthesisandfunctionalproperties
AT matveevskayavladislava coordinationpolymersbasedonhighlyemissiveligandssynthesisandfunctionalproperties
AT pavlovdmitry coordinationpolymersbasedonhighlyemissiveligandssynthesisandfunctionalproperties
AT yakunenkovandrei coordinationpolymersbasedonhighlyemissiveligandssynthesisandfunctionalproperties
AT potapovandrei coordinationpolymersbasedonhighlyemissiveligandssynthesisandfunctionalproperties