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Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties
Coordination polymers are constructed from metal ions and bridging ligands, linking them into solid-state structures extending in one (1D), two (2D) or three dimensions (3D). Two- and three-dimensional coordination polymers with potential voids are often referred to as metal-organic frameworks (MOFs...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7345804/ https://www.ncbi.nlm.nih.gov/pubmed/32545737 http://dx.doi.org/10.3390/ma13122699 |
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author | Kuznetsova, Anastasia Matveevskaya, Vladislava Pavlov, Dmitry Yakunenkov, Andrei Potapov, Andrei |
author_facet | Kuznetsova, Anastasia Matveevskaya, Vladislava Pavlov, Dmitry Yakunenkov, Andrei Potapov, Andrei |
author_sort | Kuznetsova, Anastasia |
collection | PubMed |
description | Coordination polymers are constructed from metal ions and bridging ligands, linking them into solid-state structures extending in one (1D), two (2D) or three dimensions (3D). Two- and three-dimensional coordination polymers with potential voids are often referred to as metal-organic frameworks (MOFs) or porous coordination polymers. Luminescence is an important property of coordination polymers, often playing a key role in their applications. Photophysical properties of the coordination polymers can be associated with intraligand, metal-centered, guest-centered, metal-to-ligand and ligand-to-metal electron transitions. In recent years, a rapid growth of publications devoted to luminescent or fluorescent coordination polymers can be observed. In this review the use of fluorescent ligands, namely, 4,4′-stilbenedicarboxylic acid, 1,3,4-oxadiazole, thiazole, 2,1,3-benzothiadiazole, terpyridine and carbazole derivatives, naphthalene diimides, 4,4′,4′′-nitrilotribenzoic acid, ruthenium(II) and iridium(III) complexes, boron-dipyrromethene (BODIPY) derivatives, porphyrins, for the construction of coordination polymers are surveyed. Applications of such coordination polymers based on their photophysical properties will be discussed. The review covers the literature published before April 2020. |
format | Online Article Text |
id | pubmed-7345804 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-73458042020-07-09 Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties Kuznetsova, Anastasia Matveevskaya, Vladislava Pavlov, Dmitry Yakunenkov, Andrei Potapov, Andrei Materials (Basel) Review Coordination polymers are constructed from metal ions and bridging ligands, linking them into solid-state structures extending in one (1D), two (2D) or three dimensions (3D). Two- and three-dimensional coordination polymers with potential voids are often referred to as metal-organic frameworks (MOFs) or porous coordination polymers. Luminescence is an important property of coordination polymers, often playing a key role in their applications. Photophysical properties of the coordination polymers can be associated with intraligand, metal-centered, guest-centered, metal-to-ligand and ligand-to-metal electron transitions. In recent years, a rapid growth of publications devoted to luminescent or fluorescent coordination polymers can be observed. In this review the use of fluorescent ligands, namely, 4,4′-stilbenedicarboxylic acid, 1,3,4-oxadiazole, thiazole, 2,1,3-benzothiadiazole, terpyridine and carbazole derivatives, naphthalene diimides, 4,4′,4′′-nitrilotribenzoic acid, ruthenium(II) and iridium(III) complexes, boron-dipyrromethene (BODIPY) derivatives, porphyrins, for the construction of coordination polymers are surveyed. Applications of such coordination polymers based on their photophysical properties will be discussed. The review covers the literature published before April 2020. MDPI 2020-06-13 /pmc/articles/PMC7345804/ /pubmed/32545737 http://dx.doi.org/10.3390/ma13122699 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Review Kuznetsova, Anastasia Matveevskaya, Vladislava Pavlov, Dmitry Yakunenkov, Andrei Potapov, Andrei Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties |
title | Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties |
title_full | Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties |
title_fullStr | Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties |
title_full_unstemmed | Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties |
title_short | Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties |
title_sort | coordination polymers based on highly emissive ligands: synthesis and functional properties |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7345804/ https://www.ncbi.nlm.nih.gov/pubmed/32545737 http://dx.doi.org/10.3390/ma13122699 |
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