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Properties of Dicationic Disiloxane Ionic Liquids

A number of dicationic ionic liquids with a disiloxane linker between imidazolium cations and bis(trifluoromethylsulfonyl)imide anion were synthesized and characterized. Melting points, viscosity, and volatility in a vacuum were measured; the thermal and hydrolytic stability of ionic liquids were al...

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Detalles Bibliográficos
Autores principales: Krasovskiy, Vladimir G., Kapustin, Gennady I., Gorbatsevich, Olga B., Glukhov, Lev M., Chernikova, Elena A., Koroteev, Anatoly A., Kustov, Leonid M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7355833/
https://www.ncbi.nlm.nih.gov/pubmed/32604885
http://dx.doi.org/10.3390/molecules25122949
Descripción
Sumario:A number of dicationic ionic liquids with a disiloxane linker between imidazolium cations and bis(trifluoromethylsulfonyl)imide anion were synthesized and characterized. Melting points, viscosity, and volatility in a vacuum were measured; the thermal and hydrolytic stability of ionic liquids were also studied. The dependence of the properties on the structure of substituents in the cation of the ionic liquid was demonstrated.