Properties of Dicationic Disiloxane Ionic Liquids

A number of dicationic ionic liquids with a disiloxane linker between imidazolium cations and bis(trifluoromethylsulfonyl)imide anion were synthesized and characterized. Melting points, viscosity, and volatility in a vacuum were measured; the thermal and hydrolytic stability of ionic liquids were al...

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Autores principales: Krasovskiy, Vladimir G., Kapustin, Gennady I., Gorbatsevich, Olga B., Glukhov, Lev M., Chernikova, Elena A., Koroteev, Anatoly A., Kustov, Leonid M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7355833/
https://www.ncbi.nlm.nih.gov/pubmed/32604885
http://dx.doi.org/10.3390/molecules25122949
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author Krasovskiy, Vladimir G.
Kapustin, Gennady I.
Gorbatsevich, Olga B.
Glukhov, Lev M.
Chernikova, Elena A.
Koroteev, Anatoly A.
Kustov, Leonid M.
author_facet Krasovskiy, Vladimir G.
Kapustin, Gennady I.
Gorbatsevich, Olga B.
Glukhov, Lev M.
Chernikova, Elena A.
Koroteev, Anatoly A.
Kustov, Leonid M.
author_sort Krasovskiy, Vladimir G.
collection PubMed
description A number of dicationic ionic liquids with a disiloxane linker between imidazolium cations and bis(trifluoromethylsulfonyl)imide anion were synthesized and characterized. Melting points, viscosity, and volatility in a vacuum were measured; the thermal and hydrolytic stability of ionic liquids were also studied. The dependence of the properties on the structure of substituents in the cation of the ionic liquid was demonstrated.
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spelling pubmed-73558332020-07-23 Properties of Dicationic Disiloxane Ionic Liquids Krasovskiy, Vladimir G. Kapustin, Gennady I. Gorbatsevich, Olga B. Glukhov, Lev M. Chernikova, Elena A. Koroteev, Anatoly A. Kustov, Leonid M. Molecules Article A number of dicationic ionic liquids with a disiloxane linker between imidazolium cations and bis(trifluoromethylsulfonyl)imide anion were synthesized and characterized. Melting points, viscosity, and volatility in a vacuum were measured; the thermal and hydrolytic stability of ionic liquids were also studied. The dependence of the properties on the structure of substituents in the cation of the ionic liquid was demonstrated. MDPI 2020-06-26 /pmc/articles/PMC7355833/ /pubmed/32604885 http://dx.doi.org/10.3390/molecules25122949 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Krasovskiy, Vladimir G.
Kapustin, Gennady I.
Gorbatsevich, Olga B.
Glukhov, Lev M.
Chernikova, Elena A.
Koroteev, Anatoly A.
Kustov, Leonid M.
Properties of Dicationic Disiloxane Ionic Liquids
title Properties of Dicationic Disiloxane Ionic Liquids
title_full Properties of Dicationic Disiloxane Ionic Liquids
title_fullStr Properties of Dicationic Disiloxane Ionic Liquids
title_full_unstemmed Properties of Dicationic Disiloxane Ionic Liquids
title_short Properties of Dicationic Disiloxane Ionic Liquids
title_sort properties of dicationic disiloxane ionic liquids
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7355833/
https://www.ncbi.nlm.nih.gov/pubmed/32604885
http://dx.doi.org/10.3390/molecules25122949
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