Cargando…
Electrically Conductive Nanocomposites Composed of Styrene–Acrylonitrile Copolymer and rGO via Free-Radical Polymerization
The polymerizable reduced graphene oxide (mRGO) grafted styrene–acrylonitrile copolymer composites were prepared via free radical polymerization. The graphene oxide (GO) and reduced graphene oxide (rGO) was reacted with 3-(tri-methoxysilyl)propylmethacrylate (MPS) and used as monomer to graft styren...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7362241/ https://www.ncbi.nlm.nih.gov/pubmed/32471120 http://dx.doi.org/10.3390/polym12061221 |
_version_ | 1783559464991850496 |
---|---|
author | Ko, Eun Bin Lee, Dong-Eun Yoon, Keun-Byoung |
author_facet | Ko, Eun Bin Lee, Dong-Eun Yoon, Keun-Byoung |
author_sort | Ko, Eun Bin |
collection | PubMed |
description | The polymerizable reduced graphene oxide (mRGO) grafted styrene–acrylonitrile copolymer composites were prepared via free radical polymerization. The graphene oxide (GO) and reduced graphene oxide (rGO) was reacted with 3-(tri-methoxysilyl)propylmethacrylate (MPS) and used as monomer to graft styrene and acrylonitrile on its surface. The successful modification and reduction of GO was confirmed using Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analyzer (TGA), Raman and X-ray diffraction (XRD). The mRGO was prepared using chemical and solvothermal reduction methods. The effect of the reduction method on the composite properties and nanosheet distribution in the polymer matrix was studied. The thermal stability, electrical conductivity and morphology of nanocomposites were studied. The electrical conductivity of the obtained nanocomposite was very high at 0.7 S/m. This facile free radical polymerization provides a convenient route to achieve excellent dispersion and electrically conductive polymers. |
format | Online Article Text |
id | pubmed-7362241 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-73622412020-07-21 Electrically Conductive Nanocomposites Composed of Styrene–Acrylonitrile Copolymer and rGO via Free-Radical Polymerization Ko, Eun Bin Lee, Dong-Eun Yoon, Keun-Byoung Polymers (Basel) Article The polymerizable reduced graphene oxide (mRGO) grafted styrene–acrylonitrile copolymer composites were prepared via free radical polymerization. The graphene oxide (GO) and reduced graphene oxide (rGO) was reacted with 3-(tri-methoxysilyl)propylmethacrylate (MPS) and used as monomer to graft styrene and acrylonitrile on its surface. The successful modification and reduction of GO was confirmed using Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analyzer (TGA), Raman and X-ray diffraction (XRD). The mRGO was prepared using chemical and solvothermal reduction methods. The effect of the reduction method on the composite properties and nanosheet distribution in the polymer matrix was studied. The thermal stability, electrical conductivity and morphology of nanocomposites were studied. The electrical conductivity of the obtained nanocomposite was very high at 0.7 S/m. This facile free radical polymerization provides a convenient route to achieve excellent dispersion and electrically conductive polymers. MDPI 2020-05-27 /pmc/articles/PMC7362241/ /pubmed/32471120 http://dx.doi.org/10.3390/polym12061221 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Ko, Eun Bin Lee, Dong-Eun Yoon, Keun-Byoung Electrically Conductive Nanocomposites Composed of Styrene–Acrylonitrile Copolymer and rGO via Free-Radical Polymerization |
title | Electrically Conductive Nanocomposites Composed of Styrene–Acrylonitrile Copolymer and rGO via Free-Radical Polymerization |
title_full | Electrically Conductive Nanocomposites Composed of Styrene–Acrylonitrile Copolymer and rGO via Free-Radical Polymerization |
title_fullStr | Electrically Conductive Nanocomposites Composed of Styrene–Acrylonitrile Copolymer and rGO via Free-Radical Polymerization |
title_full_unstemmed | Electrically Conductive Nanocomposites Composed of Styrene–Acrylonitrile Copolymer and rGO via Free-Radical Polymerization |
title_short | Electrically Conductive Nanocomposites Composed of Styrene–Acrylonitrile Copolymer and rGO via Free-Radical Polymerization |
title_sort | electrically conductive nanocomposites composed of styrene–acrylonitrile copolymer and rgo via free-radical polymerization |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7362241/ https://www.ncbi.nlm.nih.gov/pubmed/32471120 http://dx.doi.org/10.3390/polym12061221 |
work_keys_str_mv | AT koeunbin electricallyconductivenanocompositescomposedofstyreneacrylonitrilecopolymerandrgoviafreeradicalpolymerization AT leedongeun electricallyconductivenanocompositescomposedofstyreneacrylonitrilecopolymerandrgoviafreeradicalpolymerization AT yoonkeunbyoung electricallyconductivenanocompositescomposedofstyreneacrylonitrilecopolymerandrgoviafreeradicalpolymerization |