Ion sieving by a two-dimensional Ti(3)C(2)T(x) alginate lamellar membrane with stable interlayer spacing

Two-dimensional membranes attract extensive interest due to the anomalous transport phenomena; however, the ion separation performance is below the theoretical prediction. The stabilization of d-spacing is a key step for enhancing ion selectivity. Here, we demonstrate a strategy for stabilizing the Ti(3)C(2)T(x) laminar architecture by alginate hydrogel pillars. After pillared by Ca-alginate, the nanochannel diameters are effectively fixed at 7.4 ± 0.2 Å, and the membrane presents a permeation cutoff and an outstanding sieving property towards valent cations. When applied for acid recovery, the outstanding H(+)/Fe(2+) selectivity makes the membrane a promising substitution for traditional ion-exchange membranes. Moreover, the ultrathin Mn-alginate pillared membrane with identical d-spacing exhibits 100% Na(2)SO(4) rejection with high water permeance, which is superior to the state-of-the-art nanofiltration membranes. Building on these findings, we demonstrate an efficient method to tune the ion selectivity and introduce a new perspective for energy- and environment-related applications.