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Fe-functionalized paramagnetic sporopollenin from pollen grains: one-pot synthesis using ionic liquids

The preparation of Fe-decorated sporopollenins was achieved using pollen grains and an ionic liquid as solvent and functionalizing agent. The integrity of the organic capsules was ascertained through scanning electron microscopy studies. The presence of Fe in the capsule was investigated using FT-IR...

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Detalles Bibliográficos
Autores principales: Chiappe, C., Rodriguez-Douton, M. J., Mozzati, M. C., Prete, D., Griesi, A., Guazzelli, L., Gemmi, M., Caporali, S., Calisi, N., Pomelli, C. S., Rossella, F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7371869/
https://www.ncbi.nlm.nih.gov/pubmed/32686728
http://dx.doi.org/10.1038/s41598-020-68875-6
Descripción
Sumario:The preparation of Fe-decorated sporopollenins was achieved using pollen grains and an ionic liquid as solvent and functionalizing agent. The integrity of the organic capsules was ascertained through scanning electron microscopy studies. The presence of Fe in the capsule was investigated using FT-IR, X-ray photoemission spectroscopy and energy-dispersive X-ray spectroscopy. Electron paramagnetic resonance and magnetization measurements allowed us to demonstrate the paramagnetic behavior of our Fe-functionalized sporopollenin. A few potential applications of pollen-based systems functionalized with magnetic metal ions via ionic liquids are discussed.