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Study on the preparation of geranyl acetone and β-cyclodextrin inclusion complex and its application in cigarette flavoring

β-Cyclodextrin (β-CD) inclusion complex containing geranyl acetone as a guest was prepared by saturated water solution method. Furthermore, the structure and properties of the inclusion complex were studied. The formation of the inclusion complex was demonstrated by. Fourier transform infrared spect...

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Autores principales: Du, Fu, Pan, Tingting, Ji, Xiaoming, Hu, Jingyan, Ren, Tianbao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7378071/
https://www.ncbi.nlm.nih.gov/pubmed/32704066
http://dx.doi.org/10.1038/s41598-020-69323-1
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author Du, Fu
Pan, Tingting
Ji, Xiaoming
Hu, Jingyan
Ren, Tianbao
author_facet Du, Fu
Pan, Tingting
Ji, Xiaoming
Hu, Jingyan
Ren, Tianbao
author_sort Du, Fu
collection PubMed
description β-Cyclodextrin (β-CD) inclusion complex containing geranyl acetone as a guest was prepared by saturated water solution method. Furthermore, the structure and properties of the inclusion complex were studied. The formation of the inclusion complex was demonstrated by. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (X-RD), thermogravimetric analysis (TG) and differential scanning calorimetry (DSC). The thermodynamic analysis of the inclusion complex showed that the inclusion reaction is an endothermic spontaneous reaction. The average of △H, △S and △G is 11.66 kJ mol(−1), 0.082 kJ mol(−1) and − 14.49 kJ mol(−1), respectively. Moreover, the kinetic analysis of thermal decomposition of the inclusion compound showed that the thermal decomposition reaction is a first-order reaction (the inclusion ratio is 1:1), the average activation energy of the reaction is 180.90 kJ mol(−1), and the binding force in the inclusion compound is mainly Van der Waals force. The flavor test of cigarettes showed that the inclusion compound improved the stability of geranyl acetone and the sensory quality of cigarettes. This study improves the solubility and thermal stability of geranyl acetone, and provides theoretical support and technical guidance for expanding the application of geranyl acetone.
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spelling pubmed-73780712020-07-24 Study on the preparation of geranyl acetone and β-cyclodextrin inclusion complex and its application in cigarette flavoring Du, Fu Pan, Tingting Ji, Xiaoming Hu, Jingyan Ren, Tianbao Sci Rep Article β-Cyclodextrin (β-CD) inclusion complex containing geranyl acetone as a guest was prepared by saturated water solution method. Furthermore, the structure and properties of the inclusion complex were studied. The formation of the inclusion complex was demonstrated by. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (X-RD), thermogravimetric analysis (TG) and differential scanning calorimetry (DSC). The thermodynamic analysis of the inclusion complex showed that the inclusion reaction is an endothermic spontaneous reaction. The average of △H, △S and △G is 11.66 kJ mol(−1), 0.082 kJ mol(−1) and − 14.49 kJ mol(−1), respectively. Moreover, the kinetic analysis of thermal decomposition of the inclusion compound showed that the thermal decomposition reaction is a first-order reaction (the inclusion ratio is 1:1), the average activation energy of the reaction is 180.90 kJ mol(−1), and the binding force in the inclusion compound is mainly Van der Waals force. The flavor test of cigarettes showed that the inclusion compound improved the stability of geranyl acetone and the sensory quality of cigarettes. This study improves the solubility and thermal stability of geranyl acetone, and provides theoretical support and technical guidance for expanding the application of geranyl acetone. Nature Publishing Group UK 2020-07-23 /pmc/articles/PMC7378071/ /pubmed/32704066 http://dx.doi.org/10.1038/s41598-020-69323-1 Text en © The Author(s) 2020 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Du, Fu
Pan, Tingting
Ji, Xiaoming
Hu, Jingyan
Ren, Tianbao
Study on the preparation of geranyl acetone and β-cyclodextrin inclusion complex and its application in cigarette flavoring
title Study on the preparation of geranyl acetone and β-cyclodextrin inclusion complex and its application in cigarette flavoring
title_full Study on the preparation of geranyl acetone and β-cyclodextrin inclusion complex and its application in cigarette flavoring
title_fullStr Study on the preparation of geranyl acetone and β-cyclodextrin inclusion complex and its application in cigarette flavoring
title_full_unstemmed Study on the preparation of geranyl acetone and β-cyclodextrin inclusion complex and its application in cigarette flavoring
title_short Study on the preparation of geranyl acetone and β-cyclodextrin inclusion complex and its application in cigarette flavoring
title_sort study on the preparation of geranyl acetone and β-cyclodextrin inclusion complex and its application in cigarette flavoring
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7378071/
https://www.ncbi.nlm.nih.gov/pubmed/32704066
http://dx.doi.org/10.1038/s41598-020-69323-1
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