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Photodegradable branched polyethylenes from carbon monoxide copolymerization under benign conditions
Small amounts of in-chain keto groups render polyethylene (PE) photodegradable, a desirable feature in view of environmental plastics pollution. Free-radical copolymerization of CO and ethylene is challenging due to the formation of stable acyl radicals which hinders further chain growth. Here, we r...
Autores principales: | Morgen, Tobias O., Baur, Maximilian, Göttker-Schnetmann, Inigo, Mecking, Stefan |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7378081/ https://www.ncbi.nlm.nih.gov/pubmed/32704075 http://dx.doi.org/10.1038/s41467-020-17542-5 |
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