Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration

A transition‐metal‐free (5+1) cycloaddition of aryl‐substituted vinylcyclopropanes (VCPs) and hydrosilanes to afford silacyclohexanes is reported. Catalytic amounts of the trityl cation initiate the reaction by hydride abstraction from the hydrosilane, and further progress of the reaction is maintai...

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Detalles Bibliográficos
Autores principales: He, Tao, Wang, Guoqiang, Bonetti, Vittorio, Klare, Hendrik F. T., Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383577/
https://www.ncbi.nlm.nih.gov/pubmed/32302454
http://dx.doi.org/10.1002/anie.202004320

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383577/
https://www.ncbi.nlm.nih.gov/pubmed/32302454
http://dx.doi.org/10.1002/anie.202004320

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