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Predicting Absolute Rate Constants for Huisgen Reactions of Unsaturated Iminium Ions with Diazoalkanes

The kinetics and stereochemistry of the reactions of iminium ions derived from cinnamaldehydes and MacMillan's imidazolidinones with diphenyldiazomethane and aryldiazomethanes were investigated experimentally and with DFT calculations. The reactions of diphenyldiazomethane with iminium ions der...

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Detalles Bibliográficos
Autores principales: Zhang, Jingjing, Chen, Quan, Mayer, Robert J., Yang, Jin‐Dong, Ofial, Armin R., Cheng, Jin‐Pei, Mayr, Herbert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383640/
https://www.ncbi.nlm.nih.gov/pubmed/32259362
http://dx.doi.org/10.1002/anie.202003029

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