Oligophenyls with Multiple Disulfide Bridges as Higher Homologues of Dibenzo[c,e][1,2]dithiin: Synthesis and Application in Lithium‐Ion Batteries

Higher homologues of dibenzo[c,e][1,2]dithiin were synthesized from oligophenyls bearing multiple methylthio groups. Single‐crystal X‐ray analyses revealed their nonplanar structures and helical enantiomers of higher meta‐congener 6. Such dibenzo[1,2]dithiin homologues are demonstrated to be applica...

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Autores principales: Sonnenschein, Christoph, Ender, Christopher P., Wang, Faxing, Schollmeyer, Dieter, Feng, Xinliang, Narita, Akimitsu, Müllen, Klaus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383724/
https://www.ncbi.nlm.nih.gov/pubmed/32202685
http://dx.doi.org/10.1002/chem.202000728
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author Sonnenschein, Christoph
Ender, Christopher P.
Wang, Faxing
Schollmeyer, Dieter
Feng, Xinliang
Narita, Akimitsu
Müllen, Klaus
author_facet Sonnenschein, Christoph
Ender, Christopher P.
Wang, Faxing
Schollmeyer, Dieter
Feng, Xinliang
Narita, Akimitsu
Müllen, Klaus
author_sort Sonnenschein, Christoph
collection PubMed
description Higher homologues of dibenzo[c,e][1,2]dithiin were synthesized from oligophenyls bearing multiple methylthio groups. Single‐crystal X‐ray analyses revealed their nonplanar structures and helical enantiomers of higher meta‐congener 6. Such dibenzo[1,2]dithiin homologues are demonstrated to be applicable to lithium‐ion batteries as cathode, displaying a high capacity of 118 mAh g(−1) at a current density of 50 mA g(−1).
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spelling pubmed-73837242020-07-27 Oligophenyls with Multiple Disulfide Bridges as Higher Homologues of Dibenzo[c,e][1,2]dithiin: Synthesis and Application in Lithium‐Ion Batteries Sonnenschein, Christoph Ender, Christopher P. Wang, Faxing Schollmeyer, Dieter Feng, Xinliang Narita, Akimitsu Müllen, Klaus Chemistry Communications Higher homologues of dibenzo[c,e][1,2]dithiin were synthesized from oligophenyls bearing multiple methylthio groups. Single‐crystal X‐ray analyses revealed their nonplanar structures and helical enantiomers of higher meta‐congener 6. Such dibenzo[1,2]dithiin homologues are demonstrated to be applicable to lithium‐ion batteries as cathode, displaying a high capacity of 118 mAh g(−1) at a current density of 50 mA g(−1). John Wiley and Sons Inc. 2020-06-05 2020-06-26 /pmc/articles/PMC7383724/ /pubmed/32202685 http://dx.doi.org/10.1002/chem.202000728 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Sonnenschein, Christoph
Ender, Christopher P.
Wang, Faxing
Schollmeyer, Dieter
Feng, Xinliang
Narita, Akimitsu
Müllen, Klaus
Oligophenyls with Multiple Disulfide Bridges as Higher Homologues of Dibenzo[c,e][1,2]dithiin: Synthesis and Application in Lithium‐Ion Batteries
title Oligophenyls with Multiple Disulfide Bridges as Higher Homologues of Dibenzo[c,e][1,2]dithiin: Synthesis and Application in Lithium‐Ion Batteries
title_full Oligophenyls with Multiple Disulfide Bridges as Higher Homologues of Dibenzo[c,e][1,2]dithiin: Synthesis and Application in Lithium‐Ion Batteries
title_fullStr Oligophenyls with Multiple Disulfide Bridges as Higher Homologues of Dibenzo[c,e][1,2]dithiin: Synthesis and Application in Lithium‐Ion Batteries
title_full_unstemmed Oligophenyls with Multiple Disulfide Bridges as Higher Homologues of Dibenzo[c,e][1,2]dithiin: Synthesis and Application in Lithium‐Ion Batteries
title_short Oligophenyls with Multiple Disulfide Bridges as Higher Homologues of Dibenzo[c,e][1,2]dithiin: Synthesis and Application in Lithium‐Ion Batteries
title_sort oligophenyls with multiple disulfide bridges as higher homologues of dibenzo[c,e][1,2]dithiin: synthesis and application in lithium‐ion batteries
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383724/
https://www.ncbi.nlm.nih.gov/pubmed/32202685
http://dx.doi.org/10.1002/chem.202000728
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