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A Phosphinine‐Derived 1‐Phospha‐7‐Bora‐Norbornadiene: Frustrated Lewis Pair Type Activation of Triple Bonds
Salt metathesis of 1‐methyl‐2,4,6‐triphenylphosphacyclohexadienyl lithium and chlorobis(pentafluorophenyl)borane affords a 1‐phospha‐7‐bora‐norbornadiene derivative 2. The C≡N triple bonds of nitriles insert into the P−B bond of 2 with concomitant C−B bond cleavage, whereas the C≡C bonds of phenylac...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383905/ https://www.ncbi.nlm.nih.gov/pubmed/32052879 http://dx.doi.org/10.1002/chem.202000266 |