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Mechanically Interlocked Carbon Nanotubes as a Stable Electrocatalytic Platform for Oxygen Reduction
[Image: see text] Mechanically interlocking redox-active anthraquinone onto single-walled carbon nanotubes (AQ-MINT) gives a new and advanced example of a noncovalent architecture for an electrochemical platform. Electrochemical studies of AQ-MINT as an electrode reveal enhanced electrochemical stab...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383929/ https://www.ncbi.nlm.nih.gov/pubmed/32573248 http://dx.doi.org/10.1021/acsami.0c06516 |
Sumario: | [Image: see text] Mechanically interlocking redox-active anthraquinone onto single-walled carbon nanotubes (AQ-MINT) gives a new and advanced example of a noncovalent architecture for an electrochemical platform. Electrochemical studies of AQ-MINT as an electrode reveal enhanced electrochemical stability in both aqueous and organic solvents compared to physisorbed AQ-based electrodes. While maintaining the electrochemical properties of the parent anthraquinone molecules, we observe a stable oxygen reduction reaction to hydrogen peroxide (H(2)O(2)). Using such AQ-MINT electrodes, 7 and 2 μmol of H(2)O(2) are produced over 8 h under basic and neutral conditions, while the control system of SWCNTs produces 2.2 and 0.5 μmol, respectively. These results reveal the potential of this rotaxane-type immobilization approach for heterogenized electrocatalysis. |
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