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Modulation of the Self‐Assembly of π‐Amphiphiles in Water from Enthalpy‐ to Entropy‐Driven by Enwrapping Substituents

Depending on the connectivity of solubilizing oligoethylene glycol (OEG) side chains to the π‐cores of amphiphilic naphthalene and perylene bisimide dyes, self‐assembly in water occurs either upon heating or cooling. Herein, we show that this effect originates from differences in the enwrapping capa...

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Detalles Bibliográficos
Autores principales: Syamala, Pradeep P. N., Würthner, Frank
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7384034/
https://www.ncbi.nlm.nih.gov/pubmed/32364616
http://dx.doi.org/10.1002/chem.202000995