Photochemical Transformations with Iodine Azide after Release from an Ion‐Exchange Resin

This report discloses the photochemical homolytic cleavage of iodine azide after its formation following release from polymer‐bound bisazido iodate(I) anions. A series of radical reactions are reported including the 1,2‐functionlization of alkenes and the unprecedented chemoselective oxidation of se...

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Detalles Bibliográficos
Autores principales: Kösel, Teresa, Schulz, Göran, Dräger, Gerald, Kirschning, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7384096/
https://www.ncbi.nlm.nih.gov/pubmed/32208548
http://dx.doi.org/10.1002/anie.202003079
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author Kösel, Teresa
Schulz, Göran
Dräger, Gerald
Kirschning, Andreas
author_facet Kösel, Teresa
Schulz, Göran
Dräger, Gerald
Kirschning, Andreas
author_sort Kösel, Teresa
collection PubMed
description This report discloses the photochemical homolytic cleavage of iodine azide after its formation following release from polymer‐bound bisazido iodate(I) anions. A series of radical reactions are reported including the 1,2‐functionlization of alkenes and the unprecedented chemoselective oxidation of secondary alcohols in the presence of primary alcohols.
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spelling pubmed-73840962020-07-28 Photochemical Transformations with Iodine Azide after Release from an Ion‐Exchange Resin Kösel, Teresa Schulz, Göran Dräger, Gerald Kirschning, Andreas Angew Chem Int Ed Engl Communications This report discloses the photochemical homolytic cleavage of iodine azide after its formation following release from polymer‐bound bisazido iodate(I) anions. A series of radical reactions are reported including the 1,2‐functionlization of alkenes and the unprecedented chemoselective oxidation of secondary alcohols in the presence of primary alcohols. John Wiley and Sons Inc. 2020-04-28 2020-07-20 /pmc/articles/PMC7384096/ /pubmed/32208548 http://dx.doi.org/10.1002/anie.202003079 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Kösel, Teresa
Schulz, Göran
Dräger, Gerald
Kirschning, Andreas
Photochemical Transformations with Iodine Azide after Release from an Ion‐Exchange Resin
title Photochemical Transformations with Iodine Azide after Release from an Ion‐Exchange Resin
title_full Photochemical Transformations with Iodine Azide after Release from an Ion‐Exchange Resin
title_fullStr Photochemical Transformations with Iodine Azide after Release from an Ion‐Exchange Resin
title_full_unstemmed Photochemical Transformations with Iodine Azide after Release from an Ion‐Exchange Resin
title_short Photochemical Transformations with Iodine Azide after Release from an Ion‐Exchange Resin
title_sort photochemical transformations with iodine azide after release from an ion‐exchange resin
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7384096/
https://www.ncbi.nlm.nih.gov/pubmed/32208548
http://dx.doi.org/10.1002/anie.202003079
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