Not Guilty on Every Count: The “Non‐Innocent” Nitrosyl Ligand in the Framework of IUPAC′s Oxidation‐State Formalism

Nitrosyl–metal bonding relies on the two interactions between the pair of N–O‐π* and two of the metal's d orbitals. These (back)bonds are largely covalent, which makes their allocation in the course of an oxidation‐state determination ambiguous. However, apart from M‐N‐O‐angle or net‐charge con...

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Detalles Bibliográficos
Autores principales: Ampßler, Torsten, Monsch, Georg, Popp, Jens, Riggenmann, Tobias, Salvador, Pedro, Schröder, Daniel, Klüfers, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7384168/
https://www.ncbi.nlm.nih.gov/pubmed/32339395
http://dx.doi.org/10.1002/anie.202003122
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author Ampßler, Torsten
Monsch, Georg
Popp, Jens
Riggenmann, Tobias
Salvador, Pedro
Schröder, Daniel
Klüfers, Peter
author_facet Ampßler, Torsten
Monsch, Georg
Popp, Jens
Riggenmann, Tobias
Salvador, Pedro
Schröder, Daniel
Klüfers, Peter
author_sort Ampßler, Torsten
collection PubMed
description Nitrosyl–metal bonding relies on the two interactions between the pair of N–O‐π* and two of the metal's d orbitals. These (back)bonds are largely covalent, which makes their allocation in the course of an oxidation‐state determination ambiguous. However, apart from M‐N‐O‐angle or net‐charge considerations, IUPAC′s “ionic approximation” is a useful tool to reliably classify nitrosyl metal complexes in an orbital‐centered approach.
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spelling pubmed-73841682020-07-28 Not Guilty on Every Count: The “Non‐Innocent” Nitrosyl Ligand in the Framework of IUPAC′s Oxidation‐State Formalism Ampßler, Torsten Monsch, Georg Popp, Jens Riggenmann, Tobias Salvador, Pedro Schröder, Daniel Klüfers, Peter Angew Chem Int Ed Engl Communications Nitrosyl–metal bonding relies on the two interactions between the pair of N–O‐π* and two of the metal's d orbitals. These (back)bonds are largely covalent, which makes their allocation in the course of an oxidation‐state determination ambiguous. However, apart from M‐N‐O‐angle or net‐charge considerations, IUPAC′s “ionic approximation” is a useful tool to reliably classify nitrosyl metal complexes in an orbital‐centered approach. John Wiley and Sons Inc. 2020-05-26 2020-07-20 /pmc/articles/PMC7384168/ /pubmed/32339395 http://dx.doi.org/10.1002/anie.202003122 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Ampßler, Torsten
Monsch, Georg
Popp, Jens
Riggenmann, Tobias
Salvador, Pedro
Schröder, Daniel
Klüfers, Peter
Not Guilty on Every Count: The “Non‐Innocent” Nitrosyl Ligand in the Framework of IUPAC′s Oxidation‐State Formalism
title Not Guilty on Every Count: The “Non‐Innocent” Nitrosyl Ligand in the Framework of IUPAC′s Oxidation‐State Formalism
title_full Not Guilty on Every Count: The “Non‐Innocent” Nitrosyl Ligand in the Framework of IUPAC′s Oxidation‐State Formalism
title_fullStr Not Guilty on Every Count: The “Non‐Innocent” Nitrosyl Ligand in the Framework of IUPAC′s Oxidation‐State Formalism
title_full_unstemmed Not Guilty on Every Count: The “Non‐Innocent” Nitrosyl Ligand in the Framework of IUPAC′s Oxidation‐State Formalism
title_short Not Guilty on Every Count: The “Non‐Innocent” Nitrosyl Ligand in the Framework of IUPAC′s Oxidation‐State Formalism
title_sort not guilty on every count: the “non‐innocent” nitrosyl ligand in the framework of iupac′s oxidation‐state formalism
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7384168/
https://www.ncbi.nlm.nih.gov/pubmed/32339395
http://dx.doi.org/10.1002/anie.202003122
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