Determination of the adsorption isotherms and transport diffusivities of gases in mixtures inside zeolitic crystals using Infra-Red Micro-imaging

Different regions of Infra-Red (IR) light absorption by guest molecules inside a zeolitic crystal are measured and quantified to determine binary adsorption isotherms and transport diffusivities. This has been achieved using a vacuum capable setup which includes an Infra-Red Microscope (IRM) and Fourier Transform Infra-Red (FTIR) Spectrometer. By utilizing IR light and FTIR spectroscopy, this method can be used to describe the behavior of low concentrations of relatively fast molecules inside zeolitic crystals as an alternative to chromatographic pulse methods. To demonstrate the capabilities of this method, binary adsorption isotherms and transport diffusivities of CO(2) in mixtures composed of CO(2) and N(2) • IR microimaging with static gas dosing system for measuring transient uptake, diffusion and chemical reactions of gases and their mixtures in individual crystals or particles of nanoporous materials; • Using giant crystals the setup allows to study adsorption and transport of single components and mixtures in nanoporous materials also for fast diffusing guest molecules.