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Rigidification of Poly(p-phenylene)s through ortho-Phenyl Substitution
[Image: see text] A sterically π-congested ortho-phenylated poly(p-phenylene) (PPP) has been synthesized with unprecedentedly high molecular weights up to 29 kDa after fractionation, as confirmed by gel permeation chromatography coupled with a multiangle laser light scattering detector. The chain tr...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7392475/ https://www.ncbi.nlm.nih.gov/pubmed/32742022 http://dx.doi.org/10.1021/acs.macromol.0c00810 |