Sulfenylation of Arenes with Ethyl Arylsulfinates in Water

[Image: see text] A tetrabutylammonium iodide-mediated direct sulfenylation of arenes with ethyl arylsulfinates in water was developed. Various electron-rich arenes and ethyl arylsulfinates were investigated in the reaction, and a series of aryl sulfides were obtained in excellent yields. The advant...

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Autores principales: Wei, Yueting, He, Jing, Liu, Yali, Xu, Liang, Vaccaro, Luigi, Liu, Ping, Gu, Yanlong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7392521/
https://www.ncbi.nlm.nih.gov/pubmed/32743230
http://dx.doi.org/10.1021/acsomega.0c02590
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author Wei, Yueting
He, Jing
Liu, Yali
Xu, Liang
Vaccaro, Luigi
Liu, Ping
Gu, Yanlong
author_facet Wei, Yueting
He, Jing
Liu, Yali
Xu, Liang
Vaccaro, Luigi
Liu, Ping
Gu, Yanlong
author_sort Wei, Yueting
collection PubMed
description [Image: see text] A tetrabutylammonium iodide-mediated direct sulfenylation of arenes with ethyl arylsulfinates in water was developed. Various electron-rich arenes and ethyl arylsulfinates were investigated in the reaction, and a series of aryl sulfides were obtained in excellent yields. The advantages of this green protocol were simple reaction conditions (metal-free, water as the solvent, and under air), odorless and easily available sulfur reagent, broad substrate scope, and gram-scale synthesis. Moreover, the potential application of aryl sulfides was exemplified by further transformations.
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spelling pubmed-73925212020-07-31 Sulfenylation of Arenes with Ethyl Arylsulfinates in Water Wei, Yueting He, Jing Liu, Yali Xu, Liang Vaccaro, Luigi Liu, Ping Gu, Yanlong ACS Omega [Image: see text] A tetrabutylammonium iodide-mediated direct sulfenylation of arenes with ethyl arylsulfinates in water was developed. Various electron-rich arenes and ethyl arylsulfinates were investigated in the reaction, and a series of aryl sulfides were obtained in excellent yields. The advantages of this green protocol were simple reaction conditions (metal-free, water as the solvent, and under air), odorless and easily available sulfur reagent, broad substrate scope, and gram-scale synthesis. Moreover, the potential application of aryl sulfides was exemplified by further transformations. American Chemical Society 2020-07-13 /pmc/articles/PMC7392521/ /pubmed/32743230 http://dx.doi.org/10.1021/acsomega.0c02590 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Wei, Yueting
He, Jing
Liu, Yali
Xu, Liang
Vaccaro, Luigi
Liu, Ping
Gu, Yanlong
Sulfenylation of Arenes with Ethyl Arylsulfinates in Water
title Sulfenylation of Arenes with Ethyl Arylsulfinates in Water
title_full Sulfenylation of Arenes with Ethyl Arylsulfinates in Water
title_fullStr Sulfenylation of Arenes with Ethyl Arylsulfinates in Water
title_full_unstemmed Sulfenylation of Arenes with Ethyl Arylsulfinates in Water
title_short Sulfenylation of Arenes with Ethyl Arylsulfinates in Water
title_sort sulfenylation of arenes with ethyl arylsulfinates in water
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7392521/
https://www.ncbi.nlm.nih.gov/pubmed/32743230
http://dx.doi.org/10.1021/acsomega.0c02590
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AT guyanlong sulfenylationofareneswithethylarylsulfinatesinwater

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