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Asymmetric Dinuclear Lanthanide(III) Complexes from the Use of a Ligand Derived from 2-Acetylpyridine and Picolinoylhydrazide: Synthetic, Structural and Magnetic Studies †

A family of four Ln(III) complexes has been synthesized with the general formula [Ln(2)(NO(3))(4)(L)(2)(S)] (Ln = Gd, Tb, Er, and S = H(2)O; 1, 2 and 4, respectively/Ln = Dy, S = MeOH, complex 3), where HL is the flexible ditopic ligand N’-(1-(pyridin-2-yl)ethylidene)pyridine-2-carbohydrazide. The s...

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Detalles Bibliográficos
Autores principales: Maniaki, Diamantoula, Perlepe, Panagiota S., Pilichos, Evangelos, Christodoulou, Sotirios, Rouzières, Mathieu, Dechambenoit, Pierre, Clérac, Rodolphe, Perlepes, Spyros P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7397153/
https://www.ncbi.nlm.nih.gov/pubmed/32664199
http://dx.doi.org/10.3390/molecules25143153