Dioxygen Activation by Internally Aromatic Metallacycle: Crystallographic Structure and Mechanistic Investigations

Mononuclear metal-peroxo species are invoked as the key intermediates in metalloenzymatic or synthetic catalysis. However, either transience or sluggishness reactivity of synthetic analogs of metal-peroxo species impedes our understanding of oxygen activation mechanism. Herein, we designed and chara...

Descripción completa

Detalles Bibliográficos
Autores principales: Deng, Zhihong, Wu, Peng, Cai, Yapeng, Sui, Yanheng, Chen, Zhixin, Zhang, Hong, Wang, Binju, Xia, Haiping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7399181/
https://www.ncbi.nlm.nih.gov/pubmed/32739835
http://dx.doi.org/10.1016/j.isci.2020.101379

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7399181/
https://www.ncbi.nlm.nih.gov/pubmed/32739835
http://dx.doi.org/10.1016/j.isci.2020.101379

Ejemplares similares