Cargando…

Catalytic Cleavage of the C-O Bond in 2,6-dimethoxyphenol Without External Hydrogen or Organic Solvent Using Catalytic Vanadium Metal

Hydrogenolysis of the C-O bonds in lignin, which promises to be able to generate fuels and chemical feedstocks from biomass, is a particularly challenging and important area of investigation. Herein, we demonstrate a vanadium-catalyzed cleavage of a lignin model compound (2,6-dimethoxyphenol). The i...

Descripción completa

Detalles Bibliográficos
Autores principales:	Yu, Peng, Xie, Xue, Tan, Pengfei, Zhang, Wei, Wang, Zhiguo, Zhang, Chun, Liu, Hui
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Frontiers Media S.A. 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7399504/ https://www.ncbi.nlm.nih.gov/pubmed/32850653 http://dx.doi.org/10.3389/fchem.2020.00636

Ejemplares similares

On the Metal-Aided Catalytic Mechanism for Phosphodiester Bond Cleavage Performed by Nanozymes
por: Pecina, Adam, et al.
Publicado: (2021)

Catalytic Carbochlorocarbonylation of Unsaturated Hydrocarbons via C−COCl Bond Cleavage
por: Denton, Elliott H., et al.
Publicado: (2021)

Metal–Ligand Cooperation Facilitates Bond Activation and Catalytic Hydrogenation with Zinc Pincer Complexes
por: Rauch, Michael, et al.
Publicado: (2020)

Selective hydrogenation via precise hydrogen bond interactions on catalytic scaffolds
por: Shi, Song, et al.
Publicado: (2023)

Isoprene Polymerization: Catalytic Performance of Iminopyridine Vanadium(III) Chloride versus Vanadium(III) Chloride
por: Zhao, Mengmeng, et al.
Publicado: (2019)

Hydrogenation Kinetics of Metal Hydride Catalytic Layers
por: Bannenberg, Lars J., et al.
Publicado: (2021)

Molybdenum-, Vanadium-, and Tungsten-Containing Materials for Catalytic Applications
por: Agustin, Dominique, et al.
Publicado: (2022)

Practical Catalytic Cleavage of C(sp(3))−C(sp(3)) Bonds in Amines
por: Li, Wu, et al.
Publicado: (2019)

Molecular fusion of surfactant and Lewis-acid properties for attacking dirt by catalytic bond cleavage
por: Frisch, Marvin L., et al.
Publicado: (2021)

Dynamic Allostery Modulates Catalytic Activity by Modifying the Hydrogen Bonding Network in the Catalytic Site of Human Pin1
por: Wang, Jing, et al.
Publicado: (2017)

Catalytically Enhanced Hydrogen Sorption in Mg-MgH(2) by Coupling Vanadium-Based Catalyst and Carbon Nanotubes
por: Kadri, Atikah, et al.
Publicado: (2015)

Crystal structure of 3,4-dimethoxyphenol
por: Mills-Robles, Heather A., et al.
Publicado: (2015)

Highly Selective and Catalytic C–N Bond Cleavage of Tertiary Sulfonamides: Scope and Mechanistic Insight
por: Bhattacharya, Aditya, et al.
Publicado: (2021)

Catalytic synthesis of chloroacetates with thermoregulated ionic liquids based on vanadium-substituted polyoxometalate
por: Yan, Jingsen, et al.
Publicado: (2019)

Anticancer effects of 4-vinyl-2,6-dimethoxyphenol (canolol) against SGC-7901 human gastric carcinoma cells
por: JIANG, JING, et al.
Publicado: (2013)

Carbon Monoxide Promotes the Catalytic Hydrogenation on Metal Cluster Catalysts
por: Qin, Ruixuan, et al.
Publicado: (2020)

Alkali-metal bases in catalytic hydrogen isotope exchange processes
por: Tortajada, Andreu, et al.
Publicado: (2023)

Three critical hydrogen bonds determine the catalytic activity of the Diels–Alderase ribozyme
por: Kraut, Stefanie, et al.
Publicado: (2012)

A Quantum Mechanism Study of the C-C Bond Cleavage to Predict the Bio-Catalytic Polyethylene Degradation
por: Xu, Junyu, et al.
Publicado: (2019)

A new catalytic site functioning in antigen cleavage by H34 catalytic antibody light chain
por: Hifumi, Emi, et al.
Publicado: (2022)

Room temperature catalytic carbon–hydrogen bond alumination of unactivated arenes: mechanism and selectivity
por: Hooper, Thomas N., et al.
Publicado: (2018)

Catalytic Effect of Hydrogen Bond on Oxhydryl Dehydrogenation in Methanol Steam Reforming on Ni(111)
por: Ke, Changming, et al.
Publicado: (2020)

Intercalating lithium into the lattice of silver nanoparticles boosts catalytic hydrogenation of carbon–oxygen bonds
por: Duan, Xin-ping, et al.
Publicado: (2021)

Catalytic hydrogenation in organic synthesis : procedures and commentary /
por: Freifelder, Morris, 1907-
Publicado: (1978)

Catalytic liquefaction of municipal sewage sludge over transition metal catalysts in ethanol-water co-solvent
por: Wang, Wenjia, et al.
Publicado: (2018)

Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides
por: Luo, Jie, et al.
Publicado: (2020)

Catalytic Transfer Hydrogenation of Arenes and Heteroarenes
por: Gelis, Coralie, et al.
Publicado: (2020)

Hydrogen bonding vs. halogen bonding: the solvent decides
por: Robertson, Craig. C., et al.
Publicado: (2017)

Effect of Process Parameters on Catalytic Incineration of Solvent Emissions
por: Ojala, Satu, et al.
Publicado: (2008)

Mechanochemical Solvent‐Free Catalytic C−H Methylation
por: Ni, Shengjun, et al.
Publicado: (2020)

Catalytic conversion of diformylxylose to furfural in biphasic solvent systems
por: Huang, Lizhen, et al.
Publicado: (2023)

Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals
por: Shevick, Sophia L., et al.
Publicado: (2020)

An artificial metalloenzyme for catalytic cancer-specific DNA cleavage and operando imaging
por: Gao, Liang, et al.
Publicado: (2020)

Dissecting Solvent Effects on Hydrogen Bonding
por: Meredith, Nicole Y., et al.
Publicado: (2022)

Boosting the electronic and catalytic properties of 2D semiconductors with supramolecular 2D hydrogen-bonded superlattices
por: Wang, Can, et al.
Publicado: (2022)

A low-barrier hydrogen bond mediates antibiotic resistance in a noncanonical catalytic triad
por: Kumar, Prashasti, et al.
Publicado: (2018)

Direct evidence of a low barrier hydrogen bond in the catalytic triad of a Serine protease
por: Agback, Peter, et al.
Publicado: (2018)

Extreme Catalytic Power of Ketosteroid Isomerase Related to the Reversal of Proton Dislocations in Hydrogen-Bond Network
por: Kędzierski, Paweł, et al.
Publicado: (2020)

Hydrogen‐Bond‐Modulated Nucleofugality of Se(III) Species to Enable Photoredox‐Catalytic Semipinacol Manifolds
por: Park, Sooyoung, et al.
Publicado: (2022)

Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide
por: Singh, Palwinder, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_jnf3krpqs6aggo0a919ahimfpk