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[Pd(NHC)(μ-Cl)Cl](2): Versatile and Highly Reactive Complexes for Cross-Coupling Reactions that Avoid Formation of Inactive Pd(I) Off-Cycle Products
The development of more reactive, general, easily accessible, and readily available Pd(II)–NHC precatalysts remains a key challenge in homogeneous catalysis. In this study, we establish air-stable NHC–Pd(II) chloro-dimers, [Pd(NHC)(μ-Cl)Cl](2), as the most reactive Pd(II)–NHC catalysts developed to...
Autores principales: | Zhou, Tongliang, Ma, Siyue, Nahra, Fady, Obled, Alan M.C., Poater, Albert, Cavallo, Luigi, Cazin, Catherine S.J., Nolan, Steven P., Szostak, Michal |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7404551/ https://www.ncbi.nlm.nih.gov/pubmed/32759055 http://dx.doi.org/10.1016/j.isci.2020.101377 |
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