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Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-dichlorophenyl)-2-(2-nitrobenzylidene)hydrazine
In the title compound, C(13)H(9)Cl(2)N(3)O(2), the 2,6-dichlorophenyl ring and the nitro-substituted benzene ring form a dihedral angle of 21.16 (14)°. In the crystal, face-to-face π–π stacking interactions occur along the a-axis direction between the centroids of the 2,6-dichlorophenyl ring an...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7405556/ https://www.ncbi.nlm.nih.gov/pubmed/32843995 http://dx.doi.org/10.1107/S2056989020008567 |
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author | Çelikesir, Sevim Türktekin Akkurt, Mehmet Shikhaliyev, Namiq Q. Suleymanova, Gulnar T. Babayeva, Gulnare V. Gurbanova, Nurana V. Mammadova, Gunay Z. Bhattarai, Ajaya |
author_facet | Çelikesir, Sevim Türktekin Akkurt, Mehmet Shikhaliyev, Namiq Q. Suleymanova, Gulnar T. Babayeva, Gulnare V. Gurbanova, Nurana V. Mammadova, Gunay Z. Bhattarai, Ajaya |
author_sort | Çelikesir, Sevim Türktekin |
collection | PubMed |
description | In the title compound, C(13)H(9)Cl(2)N(3)O(2), the 2,6-dichlorophenyl ring and the nitro-substituted benzene ring form a dihedral angle of 21.16 (14)°. In the crystal, face-to-face π–π stacking interactions occur along the a-axis direction between the centroids of the 2,6-dichlorophenyl ring and the nitro-substituted benzene ring. Furthermore, these molecules show intramolecular N—H⋯Cl and C—H⋯O contacts and are linked by intermolecular N—H⋯O and C—H⋯Cl hydrogen bonds, forming pairs of hydrogen-bonded molecular layers parallel to (20[Image: see text]). The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H⋯H (23.0%), O⋯H/H⋯O (20.1%), Cl⋯H/H⋯Cl (19.0%), C⋯C (11.2%) and H⋯C/C⋯H (8.0%) interactions. |
format | Online Article Text |
id | pubmed-7405556 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-74055562020-08-24 Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-dichlorophenyl)-2-(2-nitrobenzylidene)hydrazine Çelikesir, Sevim Türktekin Akkurt, Mehmet Shikhaliyev, Namiq Q. Suleymanova, Gulnar T. Babayeva, Gulnare V. Gurbanova, Nurana V. Mammadova, Gunay Z. Bhattarai, Ajaya Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(13)H(9)Cl(2)N(3)O(2), the 2,6-dichlorophenyl ring and the nitro-substituted benzene ring form a dihedral angle of 21.16 (14)°. In the crystal, face-to-face π–π stacking interactions occur along the a-axis direction between the centroids of the 2,6-dichlorophenyl ring and the nitro-substituted benzene ring. Furthermore, these molecules show intramolecular N—H⋯Cl and C—H⋯O contacts and are linked by intermolecular N—H⋯O and C—H⋯Cl hydrogen bonds, forming pairs of hydrogen-bonded molecular layers parallel to (20[Image: see text]). The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H⋯H (23.0%), O⋯H/H⋯O (20.1%), Cl⋯H/H⋯Cl (19.0%), C⋯C (11.2%) and H⋯C/C⋯H (8.0%) interactions. International Union of Crystallography 2020-07-03 /pmc/articles/PMC7405556/ /pubmed/32843995 http://dx.doi.org/10.1107/S2056989020008567 Text en © Çelikesir et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Çelikesir, Sevim Türktekin Akkurt, Mehmet Shikhaliyev, Namiq Q. Suleymanova, Gulnar T. Babayeva, Gulnare V. Gurbanova, Nurana V. Mammadova, Gunay Z. Bhattarai, Ajaya Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-dichlorophenyl)-2-(2-nitrobenzylidene)hydrazine |
title | Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-dichlorophenyl)-2-(2-nitrobenzylidene)hydrazine |
title_full | Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-dichlorophenyl)-2-(2-nitrobenzylidene)hydrazine |
title_fullStr | Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-dichlorophenyl)-2-(2-nitrobenzylidene)hydrazine |
title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-dichlorophenyl)-2-(2-nitrobenzylidene)hydrazine |
title_short | Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-dichlorophenyl)-2-(2-nitrobenzylidene)hydrazine |
title_sort | crystal structure and hirshfeld surface analysis of (e)-1-(2,6-dichlorophenyl)-2-(2-nitrobenzylidene)hydrazine |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7405556/ https://www.ncbi.nlm.nih.gov/pubmed/32843995 http://dx.doi.org/10.1107/S2056989020008567 |
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