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Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-di­chloro­phen­yl)-2-(2-nitro­benzyl­idene)hydrazine

In the title compound, C(13)H(9)Cl(2)N(3)O(2), the 2,6-di­chloro­phenyl ring and the nitro-substituted benzene ring form a dihedral angle of 21.16 (14)°. In the crystal, face-to-face π–π stacking inter­actions occur along the a-axis direction between the centroids of the 2,6-di­chloro­phenyl ring an...

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Autores principales: Çelikesir, Sevim Türktekin, Akkurt, Mehmet, Shikhaliyev, Namiq Q., Suleymanova, Gulnar T., Babayeva, Gulnare V., Gurbanova, Nurana V., Mammadova, Gunay Z., Bhattarai, Ajaya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7405556/
https://www.ncbi.nlm.nih.gov/pubmed/32843995
http://dx.doi.org/10.1107/S2056989020008567
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author Çelikesir, Sevim Türktekin
Akkurt, Mehmet
Shikhaliyev, Namiq Q.
Suleymanova, Gulnar T.
Babayeva, Gulnare V.
Gurbanova, Nurana V.
Mammadova, Gunay Z.
Bhattarai, Ajaya
author_facet Çelikesir, Sevim Türktekin
Akkurt, Mehmet
Shikhaliyev, Namiq Q.
Suleymanova, Gulnar T.
Babayeva, Gulnare V.
Gurbanova, Nurana V.
Mammadova, Gunay Z.
Bhattarai, Ajaya
author_sort Çelikesir, Sevim Türktekin
collection PubMed
description In the title compound, C(13)H(9)Cl(2)N(3)O(2), the 2,6-di­chloro­phenyl ring and the nitro-substituted benzene ring form a dihedral angle of 21.16 (14)°. In the crystal, face-to-face π–π stacking inter­actions occur along the a-axis direction between the centroids of the 2,6-di­chloro­phenyl ring and the nitro-substituted benzene ring. Furthermore, these mol­ecules show intra­molecular N—H⋯Cl and C—H⋯O contacts and are linked by inter­molecular N—H⋯O and C—H⋯Cl hydrogen bonds, forming pairs of hydrogen-bonded mol­ecular layers parallel to (20[Image: see text]). The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H⋯H (23.0%), O⋯H/H⋯O (20.1%), Cl⋯H/H⋯Cl (19.0%), C⋯C (11.2%) and H⋯C/C⋯H (8.0%) inter­actions.
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spelling pubmed-74055562020-08-24 Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-di­chloro­phen­yl)-2-(2-nitro­benzyl­idene)hydrazine Çelikesir, Sevim Türktekin Akkurt, Mehmet Shikhaliyev, Namiq Q. Suleymanova, Gulnar T. Babayeva, Gulnare V. Gurbanova, Nurana V. Mammadova, Gunay Z. Bhattarai, Ajaya Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(13)H(9)Cl(2)N(3)O(2), the 2,6-di­chloro­phenyl ring and the nitro-substituted benzene ring form a dihedral angle of 21.16 (14)°. In the crystal, face-to-face π–π stacking inter­actions occur along the a-axis direction between the centroids of the 2,6-di­chloro­phenyl ring and the nitro-substituted benzene ring. Furthermore, these mol­ecules show intra­molecular N—H⋯Cl and C—H⋯O contacts and are linked by inter­molecular N—H⋯O and C—H⋯Cl hydrogen bonds, forming pairs of hydrogen-bonded mol­ecular layers parallel to (20[Image: see text]). The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H⋯H (23.0%), O⋯H/H⋯O (20.1%), Cl⋯H/H⋯Cl (19.0%), C⋯C (11.2%) and H⋯C/C⋯H (8.0%) inter­actions. International Union of Crystallography 2020-07-03 /pmc/articles/PMC7405556/ /pubmed/32843995 http://dx.doi.org/10.1107/S2056989020008567 Text en © Çelikesir et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Çelikesir, Sevim Türktekin
Akkurt, Mehmet
Shikhaliyev, Namiq Q.
Suleymanova, Gulnar T.
Babayeva, Gulnare V.
Gurbanova, Nurana V.
Mammadova, Gunay Z.
Bhattarai, Ajaya
Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-di­chloro­phen­yl)-2-(2-nitro­benzyl­idene)hydrazine
title Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-di­chloro­phen­yl)-2-(2-nitro­benzyl­idene)hydrazine
title_full Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-di­chloro­phen­yl)-2-(2-nitro­benzyl­idene)hydrazine
title_fullStr Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-di­chloro­phen­yl)-2-(2-nitro­benzyl­idene)hydrazine
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-di­chloro­phen­yl)-2-(2-nitro­benzyl­idene)hydrazine
title_short Crystal structure and Hirshfeld surface analysis of (E)-1-(2,6-di­chloro­phen­yl)-2-(2-nitro­benzyl­idene)hydrazine
title_sort crystal structure and hirshfeld surface analysis of (e)-1-(2,6-di­chloro­phen­yl)-2-(2-nitro­benzyl­idene)hydrazine
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7405556/
https://www.ncbi.nlm.nih.gov/pubmed/32843995
http://dx.doi.org/10.1107/S2056989020008567
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