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Crystal structure of 7,7′-[(pyridin-2-yl)methyl­ene]bis­(5-chloro­quinolin-8-ol)

In the title compound, C(24)H(15)Cl(2)N(3)O(2), one quinoline ring system is essentially planar and the other is slightly bent. An intra­molecular O—H⋯N hydrogen bond involving the hy­droxy group and a pyridine N atom forms an S(5) ring motif. In the crystal, two mol­ecules are associated into an in...

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Detalles Bibliográficos
Autores principales: Kashiwagi, Yukiyasu, Kubono, Koji, Tamai, Toshiyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7405569/
https://www.ncbi.nlm.nih.gov/pubmed/32844012
http://dx.doi.org/10.1107/S2056989020009317
Descripción
Sumario:In the title compound, C(24)H(15)Cl(2)N(3)O(2), one quinoline ring system is essentially planar and the other is slightly bent. An intra­molecular O—H⋯N hydrogen bond involving the hy­droxy group and a pyridine N atom forms an S(5) ring motif. In the crystal, two mol­ecules are associated into an inversion dimer with two R (2) (2)(7) ring motifs through inter­molecular O—H⋯N and O—H⋯O hydrogen bonds. The dimers are further linked by an inter­molecular C—H⋯O hydrogen bond and four C—H⋯π inter­actions, forming a two-dimensional network parallel to (001).