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Crystal structure of 7,7′-[(pyridin-2-yl)methylene]bis(5-chloroquinolin-8-ol)
In the title compound, C(24)H(15)Cl(2)N(3)O(2), one quinoline ring system is essentially planar and the other is slightly bent. An intramolecular O—H⋯N hydrogen bond involving the hydroxy group and a pyridine N atom forms an S(5) ring motif. In the crystal, two molecules are associated into an in...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7405569/ https://www.ncbi.nlm.nih.gov/pubmed/32844012 http://dx.doi.org/10.1107/S2056989020009317 |
Sumario: | In the title compound, C(24)H(15)Cl(2)N(3)O(2), one quinoline ring system is essentially planar and the other is slightly bent. An intramolecular O—H⋯N hydrogen bond involving the hydroxy group and a pyridine N atom forms an S(5) ring motif. In the crystal, two molecules are associated into an inversion dimer with two R (2) (2)(7) ring motifs through intermolecular O—H⋯N and O—H⋯O hydrogen bonds. The dimers are further linked by an intermolecular C—H⋯O hydrogen bond and four C—H⋯π interactions, forming a two-dimensional network parallel to (001). |
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