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Crystal structure of 7,7′-[(pyridin-2-yl)methyl­ene]bis­(5-chloro­quinolin-8-ol)

In the title compound, C(24)H(15)Cl(2)N(3)O(2), one quinoline ring system is essentially planar and the other is slightly bent. An intra­molecular O—H⋯N hydrogen bond involving the hy­droxy group and a pyridine N atom forms an S(5) ring motif. In the crystal, two mol­ecules are associated into an in...

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Autores principales: Kashiwagi, Yukiyasu, Kubono, Koji, Tamai, Toshiyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7405569/
https://www.ncbi.nlm.nih.gov/pubmed/32844012
http://dx.doi.org/10.1107/S2056989020009317
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author Kashiwagi, Yukiyasu
Kubono, Koji
Tamai, Toshiyuki
author_facet Kashiwagi, Yukiyasu
Kubono, Koji
Tamai, Toshiyuki
author_sort Kashiwagi, Yukiyasu
collection PubMed
description In the title compound, C(24)H(15)Cl(2)N(3)O(2), one quinoline ring system is essentially planar and the other is slightly bent. An intra­molecular O—H⋯N hydrogen bond involving the hy­droxy group and a pyridine N atom forms an S(5) ring motif. In the crystal, two mol­ecules are associated into an inversion dimer with two R (2) (2)(7) ring motifs through inter­molecular O—H⋯N and O—H⋯O hydrogen bonds. The dimers are further linked by an inter­molecular C—H⋯O hydrogen bond and four C—H⋯π inter­actions, forming a two-dimensional network parallel to (001).
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spelling pubmed-74055692020-08-24 Crystal structure of 7,7′-[(pyridin-2-yl)methyl­ene]bis­(5-chloro­quinolin-8-ol) Kashiwagi, Yukiyasu Kubono, Koji Tamai, Toshiyuki Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(24)H(15)Cl(2)N(3)O(2), one quinoline ring system is essentially planar and the other is slightly bent. An intra­molecular O—H⋯N hydrogen bond involving the hy­droxy group and a pyridine N atom forms an S(5) ring motif. In the crystal, two mol­ecules are associated into an inversion dimer with two R (2) (2)(7) ring motifs through inter­molecular O—H⋯N and O—H⋯O hydrogen bonds. The dimers are further linked by an inter­molecular C—H⋯O hydrogen bond and four C—H⋯π inter­actions, forming a two-dimensional network parallel to (001). International Union of Crystallography 2020-07-14 /pmc/articles/PMC7405569/ /pubmed/32844012 http://dx.doi.org/10.1107/S2056989020009317 Text en © Kashiwagi et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Kashiwagi, Yukiyasu
Kubono, Koji
Tamai, Toshiyuki
Crystal structure of 7,7′-[(pyridin-2-yl)methyl­ene]bis­(5-chloro­quinolin-8-ol)
title Crystal structure of 7,7′-[(pyridin-2-yl)methyl­ene]bis­(5-chloro­quinolin-8-ol)
title_full Crystal structure of 7,7′-[(pyridin-2-yl)methyl­ene]bis­(5-chloro­quinolin-8-ol)
title_fullStr Crystal structure of 7,7′-[(pyridin-2-yl)methyl­ene]bis­(5-chloro­quinolin-8-ol)
title_full_unstemmed Crystal structure of 7,7′-[(pyridin-2-yl)methyl­ene]bis­(5-chloro­quinolin-8-ol)
title_short Crystal structure of 7,7′-[(pyridin-2-yl)methyl­ene]bis­(5-chloro­quinolin-8-ol)
title_sort crystal structure of 7,7′-[(pyridin-2-yl)methyl­ene]bis­(5-chloro­quinolin-8-ol)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7405569/
https://www.ncbi.nlm.nih.gov/pubmed/32844012
http://dx.doi.org/10.1107/S2056989020009317
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