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Crystal structure of 7,7′-[(pyridin-2-yl)methylene]bis(5-chloroquinolin-8-ol)
In the title compound, C(24)H(15)Cl(2)N(3)O(2), one quinoline ring system is essentially planar and the other is slightly bent. An intramolecular O—H⋯N hydrogen bond involving the hydroxy group and a pyridine N atom forms an S(5) ring motif. In the crystal, two molecules are associated into an in...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7405569/ https://www.ncbi.nlm.nih.gov/pubmed/32844012 http://dx.doi.org/10.1107/S2056989020009317 |
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author | Kashiwagi, Yukiyasu Kubono, Koji Tamai, Toshiyuki |
author_facet | Kashiwagi, Yukiyasu Kubono, Koji Tamai, Toshiyuki |
author_sort | Kashiwagi, Yukiyasu |
collection | PubMed |
description | In the title compound, C(24)H(15)Cl(2)N(3)O(2), one quinoline ring system is essentially planar and the other is slightly bent. An intramolecular O—H⋯N hydrogen bond involving the hydroxy group and a pyridine N atom forms an S(5) ring motif. In the crystal, two molecules are associated into an inversion dimer with two R (2) (2)(7) ring motifs through intermolecular O—H⋯N and O—H⋯O hydrogen bonds. The dimers are further linked by an intermolecular C—H⋯O hydrogen bond and four C—H⋯π interactions, forming a two-dimensional network parallel to (001). |
format | Online Article Text |
id | pubmed-7405569 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-74055692020-08-24 Crystal structure of 7,7′-[(pyridin-2-yl)methylene]bis(5-chloroquinolin-8-ol) Kashiwagi, Yukiyasu Kubono, Koji Tamai, Toshiyuki Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(24)H(15)Cl(2)N(3)O(2), one quinoline ring system is essentially planar and the other is slightly bent. An intramolecular O—H⋯N hydrogen bond involving the hydroxy group and a pyridine N atom forms an S(5) ring motif. In the crystal, two molecules are associated into an inversion dimer with two R (2) (2)(7) ring motifs through intermolecular O—H⋯N and O—H⋯O hydrogen bonds. The dimers are further linked by an intermolecular C—H⋯O hydrogen bond and four C—H⋯π interactions, forming a two-dimensional network parallel to (001). International Union of Crystallography 2020-07-14 /pmc/articles/PMC7405569/ /pubmed/32844012 http://dx.doi.org/10.1107/S2056989020009317 Text en © Kashiwagi et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Kashiwagi, Yukiyasu Kubono, Koji Tamai, Toshiyuki Crystal structure of 7,7′-[(pyridin-2-yl)methylene]bis(5-chloroquinolin-8-ol) |
title | Crystal structure of 7,7′-[(pyridin-2-yl)methylene]bis(5-chloroquinolin-8-ol) |
title_full | Crystal structure of 7,7′-[(pyridin-2-yl)methylene]bis(5-chloroquinolin-8-ol) |
title_fullStr | Crystal structure of 7,7′-[(pyridin-2-yl)methylene]bis(5-chloroquinolin-8-ol) |
title_full_unstemmed | Crystal structure of 7,7′-[(pyridin-2-yl)methylene]bis(5-chloroquinolin-8-ol) |
title_short | Crystal structure of 7,7′-[(pyridin-2-yl)methylene]bis(5-chloroquinolin-8-ol) |
title_sort | crystal structure of 7,7′-[(pyridin-2-yl)methylene]bis(5-chloroquinolin-8-ol) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7405569/ https://www.ncbi.nlm.nih.gov/pubmed/32844012 http://dx.doi.org/10.1107/S2056989020009317 |
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