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Crystal structure and Hirshfeld surface analysis of phen­yl(5,7,8a-triphenyl-1,2,3,7,8,8a-hexa­hydro­imidazo[1,2-a]pyridin-6-yl)methanone with an unknown solvent

In the title compound, C(32)H(28)N(2)O, the imidazolidine and pyridine rings of the central hexa­hydro­imidazo[1,2-a]pyridine ring system adopt envelope and screw-boat conformations, respectively. The mol­ecule exhibits two weak intra­molecular π–π inter­actions between phenyl rings. In the crystal,...

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Autores principales: Naghiyev, Farid N., Mammadova, Gunay Z., Mamedov, Ibrahim G., Huseynova, Afet T., Çelikesir, Sevim Türktekin, Akkurt, Mehmet, Akobirshoeva, Anzurat A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7405580/
https://www.ncbi.nlm.nih.gov/pubmed/32844031
http://dx.doi.org/10.1107/S2056989020009871
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author Naghiyev, Farid N.
Mammadova, Gunay Z.
Mamedov, Ibrahim G.
Huseynova, Afet T.
Çelikesir, Sevim Türktekin
Akkurt, Mehmet
Akobirshoeva, Anzurat A.
author_facet Naghiyev, Farid N.
Mammadova, Gunay Z.
Mamedov, Ibrahim G.
Huseynova, Afet T.
Çelikesir, Sevim Türktekin
Akkurt, Mehmet
Akobirshoeva, Anzurat A.
author_sort Naghiyev, Farid N.
collection PubMed
description In the title compound, C(32)H(28)N(2)O, the imidazolidine and pyridine rings of the central hexa­hydro­imidazo[1,2-a]pyridine ring system adopt envelope and screw-boat conformations, respectively. The mol­ecule exhibits two weak intra­molecular π–π inter­actions between phenyl rings. In the crystal, mol­ecules are linked via pairs of C—H⋯ O hydrogen bonds, forming inversion dimers. The dimers are further linked by pairs of C—H⋯π inter­actions, forming infinite chains along the c-axis direction. A Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H⋯H (73.4%), C⋯H/H⋯C (18.8%) and O⋯H/H⋯O (5.7%) contacts. The contribution of some disordered solvent to the scattering was removed using the SQUEEZE routine [Spek (2015 ▸). Acta Cryst. C71, 9–18] in PLATON. The solvent contribution was not included in the reported mol­ecular weight and density.
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spelling pubmed-74055802020-08-24 Crystal structure and Hirshfeld surface analysis of phen­yl(5,7,8a-triphenyl-1,2,3,7,8,8a-hexa­hydro­imidazo[1,2-a]pyridin-6-yl)methanone with an unknown solvent Naghiyev, Farid N. Mammadova, Gunay Z. Mamedov, Ibrahim G. Huseynova, Afet T. Çelikesir, Sevim Türktekin Akkurt, Mehmet Akobirshoeva, Anzurat A. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(32)H(28)N(2)O, the imidazolidine and pyridine rings of the central hexa­hydro­imidazo[1,2-a]pyridine ring system adopt envelope and screw-boat conformations, respectively. The mol­ecule exhibits two weak intra­molecular π–π inter­actions between phenyl rings. In the crystal, mol­ecules are linked via pairs of C—H⋯ O hydrogen bonds, forming inversion dimers. The dimers are further linked by pairs of C—H⋯π inter­actions, forming infinite chains along the c-axis direction. A Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H⋯H (73.4%), C⋯H/H⋯C (18.8%) and O⋯H/H⋯O (5.7%) contacts. The contribution of some disordered solvent to the scattering was removed using the SQUEEZE routine [Spek (2015 ▸). Acta Cryst. C71, 9–18] in PLATON. The solvent contribution was not included in the reported mol­ecular weight and density. International Union of Crystallography 2020-07-24 /pmc/articles/PMC7405580/ /pubmed/32844031 http://dx.doi.org/10.1107/S2056989020009871 Text en © Naghiyev et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Naghiyev, Farid N.
Mammadova, Gunay Z.
Mamedov, Ibrahim G.
Huseynova, Afet T.
Çelikesir, Sevim Türktekin
Akkurt, Mehmet
Akobirshoeva, Anzurat A.
Crystal structure and Hirshfeld surface analysis of phen­yl(5,7,8a-triphenyl-1,2,3,7,8,8a-hexa­hydro­imidazo[1,2-a]pyridin-6-yl)methanone with an unknown solvent
title Crystal structure and Hirshfeld surface analysis of phen­yl(5,7,8a-triphenyl-1,2,3,7,8,8a-hexa­hydro­imidazo[1,2-a]pyridin-6-yl)methanone with an unknown solvent
title_full Crystal structure and Hirshfeld surface analysis of phen­yl(5,7,8a-triphenyl-1,2,3,7,8,8a-hexa­hydro­imidazo[1,2-a]pyridin-6-yl)methanone with an unknown solvent
title_fullStr Crystal structure and Hirshfeld surface analysis of phen­yl(5,7,8a-triphenyl-1,2,3,7,8,8a-hexa­hydro­imidazo[1,2-a]pyridin-6-yl)methanone with an unknown solvent
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of phen­yl(5,7,8a-triphenyl-1,2,3,7,8,8a-hexa­hydro­imidazo[1,2-a]pyridin-6-yl)methanone with an unknown solvent
title_short Crystal structure and Hirshfeld surface analysis of phen­yl(5,7,8a-triphenyl-1,2,3,7,8,8a-hexa­hydro­imidazo[1,2-a]pyridin-6-yl)methanone with an unknown solvent
title_sort crystal structure and hirshfeld surface analysis of phen­yl(5,7,8a-triphenyl-1,2,3,7,8,8a-hexa­hydro­imidazo[1,2-a]pyridin-6-yl)methanone with an unknown solvent
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7405580/
https://www.ncbi.nlm.nih.gov/pubmed/32844031
http://dx.doi.org/10.1107/S2056989020009871
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