Gaseous p–v–T Property Measurements for Titanium Tetrachloride from 873.0 to 1173.0 K and Low Pressure of 34.05 kPa

[Image: see text] For exploring the chemical reaction mechanism and the heat and the mass transfer of the TiCl(4)–Mg system in the Kroll process, it is of fundamental and practical importance to determine the gaseous p–v–T property for titanium tetrachloride at supercritical temperature and low pres...

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Autores principales: Wang, Wenhao, Wu, Fuzhong, Jin, Huixin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7407534/
https://www.ncbi.nlm.nih.gov/pubmed/32775858
http://dx.doi.org/10.1021/acsomega.0c00667
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author Wang, Wenhao
Wu, Fuzhong
Jin, Huixin
author_facet Wang, Wenhao
Wu, Fuzhong
Jin, Huixin
author_sort Wang, Wenhao
collection PubMed
description [Image: see text] For exploring the chemical reaction mechanism and the heat and the mass transfer of the TiCl(4)–Mg system in the Kroll process, it is of fundamental and practical importance to determine the gaseous p–v–T property for titanium tetrachloride at supercritical temperature and low pressure. The p–T–x data for the xTiCl(4) + (1 – x) Ar binary gas system are measured and presented in this study. Based on the Peng–Robinson (P–R) equation of state (EoS) of argon at temperatures from 873.0 to 1173.0 K, the gaseous p–v–T property of titanium tetrachloride has been estimated, and a new three-term truncated virial EoS for titanium tetrachloride is developed along 10 isotherms and 8 isodensities.
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spelling pubmed-74075342020-08-07 Gaseous p–v–T Property Measurements for Titanium Tetrachloride from 873.0 to 1173.0 K and Low Pressure of 34.05 kPa Wang, Wenhao Wu, Fuzhong Jin, Huixin ACS Omega [Image: see text] For exploring the chemical reaction mechanism and the heat and the mass transfer of the TiCl(4)–Mg system in the Kroll process, it is of fundamental and practical importance to determine the gaseous p–v–T property for titanium tetrachloride at supercritical temperature and low pressure. The p–T–x data for the xTiCl(4) + (1 – x) Ar binary gas system are measured and presented in this study. Based on the Peng–Robinson (P–R) equation of state (EoS) of argon at temperatures from 873.0 to 1173.0 K, the gaseous p–v–T property of titanium tetrachloride has been estimated, and a new three-term truncated virial EoS for titanium tetrachloride is developed along 10 isotherms and 8 isodensities. American Chemical Society 2020-07-23 /pmc/articles/PMC7407534/ /pubmed/32775858 http://dx.doi.org/10.1021/acsomega.0c00667 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Wang, Wenhao
Wu, Fuzhong
Jin, Huixin
Gaseous p–v–T Property Measurements for Titanium Tetrachloride from 873.0 to 1173.0 K and Low Pressure of 34.05 kPa
title Gaseous p–v–T Property Measurements for Titanium Tetrachloride from 873.0 to 1173.0 K and Low Pressure of 34.05 kPa
title_full Gaseous p–v–T Property Measurements for Titanium Tetrachloride from 873.0 to 1173.0 K and Low Pressure of 34.05 kPa
title_fullStr Gaseous p–v–T Property Measurements for Titanium Tetrachloride from 873.0 to 1173.0 K and Low Pressure of 34.05 kPa
title_full_unstemmed Gaseous p–v–T Property Measurements for Titanium Tetrachloride from 873.0 to 1173.0 K and Low Pressure of 34.05 kPa
title_short Gaseous p–v–T Property Measurements for Titanium Tetrachloride from 873.0 to 1173.0 K and Low Pressure of 34.05 kPa
title_sort gaseous p–v–t property measurements for titanium tetrachloride from 873.0 to 1173.0 k and low pressure of 34.05 kpa
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7407534/
https://www.ncbi.nlm.nih.gov/pubmed/32775858
http://dx.doi.org/10.1021/acsomega.0c00667
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